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In Vivo Biocatalytic Cascades Featuring an Artificial-Enzyme-Catalysed New-to-Nature Reaction**

Biocatalytic Friedel-Crafts Reactions

Tandem Friedel-Crafts-Alkylation-Enantioselective-Protonation by Artificial Enzyme Iminium Catalysis

A Water-Soluble Iridium Photocatalyst for Chemical Modification of Dehydroalanines in Peptides and Proteins

Chemogenetic Tags with Probe Exchange for Live-Cell Fluorescence Microscopy

In vivo Assembly of Artificial Metalloenzymes and Application in Whole-Cell Biocatalysis

Merging Whole-cell Biosynthesis of Styrene and Transition-metal Catalyzed Derivatization Reactions

Rapid and selective chemical editing of Ribosomally synthesized and Post-translationally modified Peptides (RiPPs) via Cu(II)-catalyzed β-borylation of dehydroamino acids

Repurposed and artificial heme enzymes for cyclopropanation reactions

Synergistic Catalysis of Tandem Michael Addition/Enantioselective Protonation Reactions by an Artificial Enzyme

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