Manganese catalysed oxidations with hydrogen peroxide. Applications and mechanistic insights
PhD ceremony: Ms. P. Saisaha, 12.45 uur, Academiegebouw, Broerstraat 5, Groningen
Dissertation: Manganese catalysed oxidations with hydrogen peroxide. Applications and mechanistic insights
Promotor(s): prof. B.L. Feringa
Faculty: Mathematics and Natural Sciences
The central aim of the research described in this thesis was to develop new environmentally and economically sustainable methods for the selective oxidation of organic compounds, especially the cis-dihydroxylation and epoxidation of alkenes, the oxidation of alcohols, aldehydes and selective C-H activation.
The key challenge was to carry out these reactions using a simple manganese catalyst and hydrogen peroxide. A major advance was made very early in the research project with the discovery of a completely new catalyst concept with immediate applications in the research laboratory and for industrial applications and which was subsequently patented together with industrial project partners. The main focus of the PhD work was to unravel how this catalyst system works and to provide key insights that allow for even wider applications in the future.
Last modified: | 13 March 2020 01.01 a.m. |
More news
-
10 September 2025
Funding for Feringa and Minnaard from National Growth Fund project Big Chemistry
Two UG research projects have received funding from the National Growth Fund project Big Chemistry via NWO.
-
09 September 2025
The carbon cycle as Earth’s thermostat
Earth's natural carbon cycle becomes unbalanced if we, humans, continue to release extra carbon dioxide (CO2) into the atmosphere. In this overview article about the carbon cycle, you can find out how Earth generally keeps itself in balance and how...
-
09 September 2025
Carbon dioxide’s fingerprint
In the year 2000, Harro Meijer, Professor of Isotope Physics at the University of Groningen, set up the Lutjewad Measurement Station near Hornhuizen. There, researchers from Groningen are mapping where CO2 in the atmosphere originates and where it...