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Research Zernike (ZIAM) Macromolecular Chemistry and New Polymeric Materials Portale Group

Publications

2022

Xu, F., Crespi, S., Pacella, G., Fu, Y., Stuart, M. C. A., Zhang, Q., Portale, G., & Feringa, B. L. (2022). Dynamic Control of a Multistate Chiral Supramolecular Polymer in Water. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.2c01063
Gahlot, K., de Graaf, S., Duim, H., Nedelcu, G., Koushki, R. M., Ahmadi, M., Gavhane, D., Lasorsa, A., De Luca, O., Rudolf, P., van der Wel, P. C. A., Loi, M. A., Kooi, B. J., Portale, G., Calbo, J., & Protesescu, L. (2022). Structural Dynamics and Tunability for Colloidal Tin Halide Perovskite Nanostructures. Advanced materials, [e2201353]. https://doi.org/10.1002/adma.202201353

2021

Kathan, M., Crespi, S., Thiel, N. O., Stares, D. L., Morsa, D., de Boer, J., Pacella, G., van den Enk, T., Kobauri, P., Portale, G., Schalley, C. A., & Feringa, B. L. (2022). A light-fuelled nanoratchet shifts a coupled chemical equilibrium. Nature Nanotechnology, 17, 159-165. https://doi.org/10.1038/s41565-021-01021-z
Dong, J., Gerlach, D., Koutsogiannis, P., Rudolf, P., & Portale, G. (2021). Boosting the Thermoelectric Properties of PEDOT: PSS via Low-Impact Deposition of Tin Oxide Nanoparticles. Advanced electronic materials, 7(5), [2001284]. https://doi.org/10.1002/aelm.202001284
Garcia Romero, D., Di Mario, L., Portale, G., & Loi, M. A. (2021). Crystallization driven boost in fill factor and stability in additive-free organic solar cells. Journal of Materials Chemistry A, 9(42), 23783-23792. https://doi.org/10.1039/d1ta08232a
Saidi, S., Portale, G., Bras, W., Longo, A., Amigo, J. M., Chapron, D., Bourson, P., & Hermida-Merino, D. (2021). Data Mining of Polymer Phase Transitions upon Temperature Changes by Small and Wide-Angle X-ray Scattering Combined with Raman Spectroscopy. Polymers, 13(23), [4203]. https://doi.org/10.3390/polym13234203
Dong, J., Liu, J., Qiu, X., Chiechi, R., Koster, L. J. A., & Portale, G. (2021). Engineering the Thermoelectrical Properties of PEDOT: PSS by Alkali Metal Ion Effect. Engineering, 7(5), 647-654. https://doi.org/10.1016/j.eng.2021.02.011
Shao, S., Talsma, W., Pitaro, M., Dong, J., Kahmann, S., Rommens, A. J., Portale, G., & Loi, M. A. (2021). Field-Effect Transistors Based on Formamidinium Tin Triiodide Perovskite. Advanced Functional Materials, 31(11), [2008478]. https://doi.org/10.1002/adfm.202008478
Dong, J., Sami, S., Balazs, D. M., Alessandri, R., Jahani, F., Qiu, L., Marrink, S. J., Havenith, R. W. A., Hummelen, J. C., Loi, M. A., & Portale, G. (2021). Fullerene derivatives with oligoethylene-glycol side chains: An investigation on the origin of their outstanding transport properties. Journal of Materials Chemistry C, 9(45), 16217-16225. https://doi.org/10.1039/d1tc02753k
Shao, S., Nijenhuis, M., Dong, J., Kahmann, S., ten Brink, G. H., Portale, G., & Loi, M. A. (2021). Influence of the stoichiometry of tin-based 2D/3D perovskite active layers on solar cell performance. Journal of Materials Chemistry A, 9(16), 10095-10103 . https://doi.org/10.1039/d0ta10277f
Liu, J., Van Der Zee, B., Villava, D. R., Ye, G., Kahmann, S., Kamperman, M., Dong, J., Qiu, L., Portale, G., Loi, M. A., Hummelen, J. C., Chiechi, R. C., Baran, D., & Koster, L. J. A. (2021). Molecular Doping Directed by a Neutral Radical. ACS Applied Materials and Interfaces, 13(25), 29858–29865. https://doi.org/10.1021/acsami.1c03411
Viviani, M., Fluitman, S. P., Loos, K., & Portale, G. (2021). Proton conducting ABA triblock copolymers with sulfonated poly(phenylene sulfide sulfone) midblock obtained via copper-free thiol-click chemistry dagger. Polymer Chemistry, 12(17), [2563-2571 ]. https://doi.org/10.1039/d1py00094b
Di Sacco, F., Saidi, S., Hermida-Merino, D., & Portale, G. (2021). Revisiting the Mechanism of the Meso-to-α Transition of Isotactic Polypropylene and Ethylene-Propylene Random Copolymers. Macromolecules, 54(20), 9681–9691. https://doi.org/10.1021/acs.macromol.1c01904
Xi, J., Duim, H., Pitaro, M., Gahlot, K., Dong, J., Portale, G., & Loi, M. A. (2021). Scalable, Template Driven Formation of Highly Crystalline Lead-Tin Halide Perovskite Films. Advanced Functional Materials, 31(46), [2105734]. https://doi.org/10.1002/adfm.202105734
Giordano, M. C., di Sacco, F., Barelli, M., Portale, G., & de Mongeot, F. B. (2021). Self-Organized Tailoring of Faceted Glass Nanowrinkles for Organic Nanoelectronics. ACS Applied Nano Materials, 4(2), 1940-1950. https://doi.org/10.1021/acsanm.0c03290
Yu, L., Portale, G., & Stingelin, N. (2021). Solution-processing of semiconducting organic small molecules: What we have learnt from 5,11-bis(triethylsilylethynyl)anthradithiophene. Journal of Materials Chemistry C, 9(33), 10547-10556. https://doi.org/10.1039/d1tc01418h
Komáromy, D., Tiemersma-Wegman, T., Kemmink, J., Portale, G., Adamski, P. R., Blokhuis, A., Aalbers, F. S., Marić, I., Santiago, G. M., Ottelé, J., Sood, A., Saggiomo, V., Liu, B., van der Meulen, P., & Otto, S. (2021). Stoichiometry alone can steer supramolecular systems on complex free energy surfaces with high selectivity. Chem, 7(7), 1933-1951. https://doi.org/10.1016/j.chempr.2021.05.020
Viviani, M., Lova, P., & Portale, G. (2021). Structural Transitions During Formation and Rehydration of Proton Conducting Polymeric Membranes. Macromolecular Rapid Communications, 42(12), [2000717]. https://doi.org/10.1002/marc.202000717

2020

Liu, K., Sun, J., Ma, C., Maity, S., Wang, F., Zhou, Y., Portale, G., Göstl, R., Roos, W. H., Zhang, H., & Herrmann, A. (2021). Reversibly photo-modulating mechanical stiffness and toughness of bioengineered protein fibers. Angewandte Chemie (International ed. in English), 60(6), 3222-3228. https://doi.org/10.1002/anie.202012848
Liu, J., Ye, G., Potgieser, H. G. O., Koopmans, M., Sami, S., Nugraha, M. I., Villalva, D. R., Sun, H., Dong, J., Yang, X., Qiu, X., Yao, C., Portale, G., Fabiano, S., Anthopoulos, T. D., Baran, D., Havenith, R. W. A., Chiechi, R. C., & Koster, L. J. A. (2020). Amphipathic Side Chain of a Conjugated Polymer Optimizes Dopant Location toward Efficient N-Type Organic Thermoelectrics. Advanced materials, [2006694]. https://doi.org/10.1002/adma.202006694
Abdu-Aguye, M., Doumon, N. Y., Terzic, I., Dong, J., Portale, G., Loos, K., Koster, L. J. A., & Loi, M. A. (2020). Can Ferroelectricity Improve Organic Solar Cells? Macromolecular Rapid Communications, 41(11), [2000124]. https://doi.org/10.1002/marc.202000124
Saxena, V., & Portale, G. (2020). Contribution of Ex-Situ and In-Situ X-ray Grazing Incidence Scattering Techniques to the Understanding of Quantum Dot Self-Assembly: A Review. Nanomaterials, 10(11), 1-24. [2240]. https://doi.org/10.3390/nano10112240
Ma, C., Dong, J., Viviani, M., Tulini, I., Pontillo, N., Maity, S., Zhou, Y., Roos, W. H., Liu, K., Herrmann, A., & Portale, G. (2020). De novo rational design of a freestanding, supercharged polypeptide, proton-conducting membrane. Science Advances, 6(29), [0810]. https://doi.org/10.1126/sciadv.abc0810
Novak, S., Zhang, J., Kentzinger, E., Rücker, U., Portale, G., Jung, N., Jonas, U., Myung, J. S., Winkler, R. G., Gompper, G., Dhont, J. K. G., & Stiakakis, E. (2020). DNA Self-Assembly Mediated by Programmable Soft-Patchy Interactions. Acs Nano, 14(10), 13524–13535. https://doi.org/10.1021/acsnano.0c05536
Koopmans, M., Leiviskä, M. A. T., Liu, J., Dong, J., Qiu, L., Hummelen, J. C., Portale, G., Heiber, M. C., & Koster, L. J. A. (2020). Electrical Conductivity of Doped Organic Semiconductors Limited by Carrier-Carrier Interactions. ACS Applied Materials & Interfaces, 12(50), 56222-56230. https://doi.org/10.1021/acsami.0c15490
Potsi, G., Wu, J., Portale, G., Gengler, R. Y. N., Longo, A., Gournis, D., & Rudolf, P. (2020). Fabrication of highly ordered Cu2+/Fe3+ decorated polyhedral oligomeric silsesquioxane hybrids: How metal coordination influences structure. Journal of Colloid and Interface Science, 572, 207-215. https://doi.org/10.1016/j.jcis.2020.03.033
Viviani, M., Fluitman, S. P., Loos, K., & Portale, G. (2020). Highly Stable Membranes of Poly(phenylene sulfide benzimidazole) Cross-Linked with Polyhedral Oligomeric Silsesquioxanes for High-Temperature Proton Transport. ACS Applied Energy Materials, 3(8), 7873-7884. https://doi.org/10.1021/acsaem.0c01285
Wang, Q., Shao, S., Xu, B., Duim, H., Dong, J., Adjokatse, S., Portale, G., Hou, J., Saba, M., & Loi, M. A. (2020). Impact of the Hole Transport Layer on the Charge Extraction of Ruddlesden-Popper Perovskite Solar Cells. ACS Applied Materials & Interfaces, 12(26), 29505–29512. https://doi.org/10.1021/acsami.0c05290
Xu, Y., Nudelman, F., Eren, E. D., Wirix, M. J. M., Cantaert, B., Nijhuis, W. H., Hermida-Merino, D., Portale, G., Bomans, P. H. H., Ottmann, C., Friedrich, H., Bras, W., Akiva, A., Orgel, J. P. R. O., Meldrum, F. C., & Sommerdijk, N. (2020). Intermolecular channels direct crystal orientation in mineralized collagen. Nature Communications, 11(1), [5068]. https://doi.org/10.1038/s41467-020-18846-2
Yang, B., & Portale, G. (2020). Ionic thermoelectric materials for waste heat harvesting. Colloid and Polymer Science. https://doi.org/10.1007/s00396-020-04792-4
Viviani, M., Meereboer, N. L., Saraswati, N. L. P. A., Loos, K., & Portale, G. (2020). Lithium and magnesium polymeric electrolytes prepared using poly(glycidyl ether)-based polymers with short grafted chains. Polymer Chemistry, 11(12), 2070-2079. https://doi.org/10.1039/c9py01735f
Dong, J., Shao, S., Kahmann, S., Rommens, A. J., Hermida-Merino, D., ten Brink, G. H., Loi, M. A., & Portale, G. (2020). Mechanism of Crystal Formation in Ruddlesden-Popper Sn-Based Perovskites. Advanced Functional Materials, 30(24), [2001294]. https://doi.org/10.1002/adfm.202001294
Jansen, K. A., Zhmurov, A., Vos, B. E., Portale, G., Hermida-Merino, D., Litvinov, R., Tutwiler, V., Kurniawan, N. A., Bras, W., Weisel, J. W., Barsegov, V., & Koenderink, G. H. (2020). Molecular packing structure of fibrin fibers resolved by X-ray scattering and molecular modeling. Soft Matter, 16(35), 8272-8283. https://doi.org/10.1039/d0sm00916d
Portale, G. (2020). Novel engineered proteins for mechanomaterials. Frontiers of chemical science and engineering, 14(6), 1122-1123. https://doi.org/10.1007/s11705-020-1941-x
Liu, J., van der Zee, B., Alessandri, R., Sami, S., Dong, J., Nugraha, M. I., Barker, A. J., Rousseva, S., Qiu, L., Qiu, X., Klasen, N., Chiechi, R. C., Baran, D., Caironi, M., Anthopoulos, T. D., Portale, G., Havenith, R. W. A., Marrink, S. J., Hummelen, J. C., & Koster, L. J. A. (2020). N-type organic thermoelectrics: demonstration of ZT > 0.3. Nature Communications, 11(1), [5694]. https://doi.org/10.1038/s41467-020-19537-8
Bederak, D., Sukharevska, N., Kahmann, S., Abdu-Aguye, M., Duim, H., Dirin, D. N., Kovalenko, M., Portale, G., & Loi, M. A. (2020). On the Colloidal Stability of PbS Quantum Dots Capped with Methylammonium Lead Iodide Ligands. ACS Applied Materials & Interfaces, 12(47), 52959-52966. https://doi.org/10.1021/acsami.0c16646
Golkaram, M., Portale, G., Mulder, P., Maniar, D., Faraji, S., & Loos, K. (2020). Order-disorder transition in supramolecular polymer combs/brushes with polymeric side chains. Polymer Chemistry, 11(15), 2749-2760. https://doi.org/10.1039/c9py01915d
Groeneveld, B. G. H. M., Duim, H., Kahmann, S., De Luca, O., Tekelenburg, E. K., Kamminga, M. E., Protesescu, L., Portale, G., Blake, G. R., Rudolf, P., & Loi, M. A. (2020). Photochromism in Ruddlesden-Popper copper-based perovskites: A light-induced change of coordination number at the surface. Journal of Materials Chemistry C, 8(43), 15377-15384. https://doi.org/10.1039/d0tc03359f
Cummins, C., Mantione, D., Cruciani, F., Pino, G., Demazy, N., Shi, Y., Portale, G., Hadziioannou, G., & Fleury, G. (2020). Rapid Self-Assembly and Sequential Infiltration Synthesis of High χ Fluorine-Containing Block Copolymers. Macromolecules, 53(15), 6246-6254. https://doi.org/10.1021/acs.macromol.0c01148
Dong, J., & Portale, G. (2020). Role of the Processing Solvent on the Electrical Conductivity of PEDOT: PSS. Advanced Materials Interfaces, 7(18), [2000641]. https://doi.org/10.1002/admi.202000641
Patmanidis, I., de Vries, A. H., Wassenaar, T. A., Wang, W., Portale, G., & Marrink, S. J. (2020). Structural characterization of supramolecular hollow nanotubes with atomistic simulations and SAXS. PPCP : Physical Chemistry Chemical Physics, 22(37), 21083-21093. [D0CP03282D]. https://doi.org/10.1039/d0cp03282d
Golkaram, M., van Ruymbeke, E., Portale, G., & Loos, K. (2020). Supramolecular Polymer Brushes: Influence of Molecular Weight and Cross-Linking on Linear Viscoelastic Behavior. Macromolecules, 53(12), 4810-4820. https://doi.org/10.1021/acs.macromol.0c00074
Dendooven, J., Van Daele, M., Solano, E., Ramachandran, R. K., Minjauw, M. M., Resta, A., Vlad, A., Garreau, Y., Coati, A., Portale, G., & Detavernier, C. (2020). Surface mobility and impact of precursor dosing during atomic layer deposition of platinum: In situ monitoring of nucleation and island growth. PPCP : Physical Chemistry Chemical Physics, 22(43), 24917-24933. https://doi.org/10.1039/d0cp03563g
Di Sacco, F., Gahleitner, M., Wang, J., & Portale, G. (2020). Systematic Investigation on the Structure-Property Relationship in Isotactic Polypropylene Films Processed via Cast Film Extrusion. Polymers, 12(8), [1636]. https://doi.org/10.3390/polym12081636
Qiu, X., Ivasyshyn, V., Qiu, L., Enache, M., Dong, J., Rousseva, S., Portale, G., Stöhr, M., Hummelen, J. C., & Chiechi, R. C. (2020). Thiol-free self-assembled oligoethylene glycols enable robust air-stable molecular electronics. Nature Materials, 19, 330-337. https://doi.org/10.1038/s41563-019-0587-x
Shao, S., Duim, H., Wang, Q., Xu, B., Dong, J., Adjokatse, S., Blake, G. R., Protesescu, L., Portale, G., Hou, J., Saba, M., & Loi, M. A. (2020). Tuning the Energetic Landscape of Ruddlesden-Popper Perovskite Films for Efficient Solar Cells. ACS Energy Letters, 5(1), 39-46. https://doi.org/10.1021/acsenergylett.9b02397

2019

Crespo, M., Santagiuliana, G., Picot, O., Portale, G., Bilotti, E., & Gautrot, J. E. (2019). A Photoaddressable Liquid Crystalline Phase Transition in Graphene Oxide Nanocomposites. Advanced Functional Materials, 29(24), [1900738]. https://doi.org/10.1002/adfm.201900738
Aissou, K., Mumtaz, M., Bouzit, H., Pecastaings, G., Portale, G., Fleury, G., & Hadziioannou, G. (2019). Bicontinuous Network Nanostructure with Tunable Thickness Formed on Asymmetric Triblock Terpolymer Thick Films. Macromolecules, 52(12), 4413-4420. https://doi.org/10.1021/acs.macromol.9b00572
Xu, J., Varghese, J., Portale, G., Longo, A., Momand, J., Syari'ati, A., Heuver, J. A., Rudolf, P., Kooi, B. J., Noheda, B., & Loos, K. (2019). Chemical Solution Deposition of Ordered 2D Arrays of Room-Temperature Ferrimagnetic Cobalt Ferrite Nanodots. Polymers, 11(10), [1598]. https://doi.org/10.3390/polym11101598
de Almeida, P., Jaspers, M., Vaessen, S., Tagit, O., Portale, G., Rowan, A. E., & Kouwer, P. H. J. (2019). Cytoskeletal stiffening in synthetic hydrogels. Nature Communications, 10, [609]. https://doi.org/10.1038/s41467-019-08569-4
Liu, J., Garman, M. P., Dong, J., van der Zee, B., Qiu, L., Portale, G., Hummelen, J. C., & Koster, L. J. A. (2019). Doping Engineering Enables Highly Conductive and Thermally Stable n-Type Organic Thermoelectrics with High Power Factor. ACS Applied Energy Materials, 2(9), 6664-6671. https://doi.org/10.1021/acsaem.9b01179
Terzic, I., Meereboer, N. L., Acuautla, M., Portale, G., & Loos, K. (2019). Electroactive materials with tunable response based on block copolymer self-assembly. Nature Communications, 10, [601]. https://doi.org/10.1038/s41467-019-08436-2
Chakraborty, G., Balinin, K., Portale, G., Loznik, M., Polushkin, E., Weil, T., & Herrmann, A. (2019). Electrostatically PEGylated DNA enables salt-free hybridization in water. Chemical Science, 10(43), 10097-10105. https://doi.org/10.1039/c9sc02598g
Doumon, N. Y., Houard, F. V., Dong, J., Yao, H., Portale, G., Hou, J., & Koster, L. (2019). Energy level modulation of ITIC derivatives: Effects on the photodegradation of conventional and inverted organic solar cells. Organic Electronics, 69, 255-262. https://doi.org/10.1016/j.orgel.2019.03.037
Shao, S., Dong, J., Duim, H., ten Brink, G. H., Blake, G. R., Portale, G., & Loi, M. A. (2019). Enhancing the crystallinity and perfecting the orientation of formamidinium tin iodide for highly efficient Sn-based perovskite solar cells. Nano energy, 60, 810-816. https://doi.org/10.1016/j.nanoen.2019.04.040
Gasparini, N., Kahmann, S., Salvador, M., Perea, J. D., Sperlich, A., Baumann, A., Li, N., Rechberger, S., Spiecker, E., Dyakonov, V., Portale, G., Loi, M. A., Brabec, C. J., & Ameri, T. (2019). Favorable Mixing Thermodynamics in Ternary Polymer Blends for Realizing High Efficiency Plastic Solar Cells. Advanced Energy Materials, 9(19), [1803394]. https://doi.org/10.1002/aenm.201803394
Meereboer, N. L., Terzic, I., Portale, G., & Loos, K. (2019). Improved energy density and charge-discharge efficiency in solution processed highly defined ferroelectric block copolymer-based dielectric nanocomposites. Nano energy, 64, [103939]. https://doi.org/10.1016/j.nanoen.2019.103939
Doumon, N. Y., Houard, F. V., Dong, J., Christodoulis, P., Dryzhov, M. V., Portale, G., & Koster, L. (2019). Improved photostability in ternary blend organic solar cells: The role of [70]PCBM. Journal of Materials Chemistry C, 7(17), 5104-5111. https://doi.org/10.1039/c8tc06621c
McKibbin, S. R., Yngman, S., Balmes, O., Meuller, B. O., Tagerud, S., Messing, M. E., Portale, G., Sztucki, M., Deppert, K., Samuelson, L., Magnusson, M. H., Lundgren, E., & Mikkelsen, A. (2019). In situ observation of synthesized nanoparticles in ultra-dilute aerosols via X-ray scattering. Nano Research, 12(1), 25-31. https://doi.org/10.1007/s12274-018-2170-1
McKibbin, S. R., Yngman, S., Balmes, O., Meuller, B. O., Tagerud, S., Messing, M. E., Portale, G., Sztucki, M., Deppert, K., Samuelson, L., Magnusson, M. H., Lundgren, E., & Mikkelsen, A. (2019). In situ observation of synthesized nanoparticles in ultra-dilute aerosols via X-ray scattering (vol 12, pg 25, 2019). Nano Research, 12(3), 701-701. https://doi.org/10.1007/s12274-018-2253-z
Vagias, A., Chen, Q., ten Brink, G. H., Hermida-Merino, D., Scheerder, J., & Portale, G. (2019). Investigation of the Nanoscale Morphology in Industrially Relevant Clearcoats of Waterborne Polymer Colloids by Means of Variable-Angle-Grazing Incidence Small-Angle X-ray Scattering. ACS Applied Polymer Materials, 1(9), 2482-2494. https://doi.org/10.1021/acsapm.9b00601
Fleury, G., Hermida-Merino, D., Dong Jingjin, Aissou, K., Bytchkov, A., & Portale, G. (2019). Micellar-Mediated Block Copolymer Ordering Dynamics Revealed by In Situ Grazing Incidence Small-Angle X-Ray Scattering during Spin Coating. Advanced Functional Materials, 29(10), [1806741]. https://doi.org/10.1002/adfm.201806741
Alauhdin, M., Bennett, T. M., He, G., Bassett, S. P., Portale, G., Bras, W., Hermida-Merino, D., & Howdle, S. M. (2019). Monitoring morphology evolution within block copolymer microparticles during dispersion polymerisation in supercritical carbon dioxide: a high pressure SAXS study. Polymer Chemistry, 10(7), 860-871. https://doi.org/10.1039/c8py01578c
Liu, J., Shi, Y., Dong, J., Nugraha, M. I., Qiu, X., Su, M., Chiechi, R. C., Baran, D., Portale, G., Guo, X., & Koster, L. J. A. (2019). Overcoming Coulomb Interaction Improves Free-Charge Generation and Thermoelectric Properties for n-Doped Conjugated Polymers. ACS Energy Letters, 4(7), 1556-1564. https://doi.org/10.1021/acsenergylett.9b00977
Meereboer, N., Terzic, I., van der Steeg, P., Portale, G., & Loos, K. (2019). Physical pinning and chemical crosslinking-induced relaxor ferroelectric behavior in P(VDF-ter-TrFE-ter-VA) terpolymers. Journal of Materials Chemistry A, 7(6), 2795-2803. https://doi.org/10.1039/c8ta11534f
Meereboer, N. L., Terzic, I., Mellema, H. H., Portale, G., & Loos, K. (2019). Pronounced Surface Effects on the Curie Transition Temperature in Nanoconfined P(VDF-TrFE) Crystals. Macromolecules, 52(4), 1567-1576. https://doi.org/10.1021/acs.macromol.8b02382
Groeneveld, B. G. H. M., Adjokatse, S., Nazarenko, O., Fang, H-H., Blake, G. R., Portale, G., Duim, H., ten Brink, G. H., Kovalenko, M., & Loi, M. A. (2019). Stable Cesium Formamidinium Lead Halide Perovskites: A Comparison of Photophysics and Phase Purity in Thin Films and Single Crystals. Energy Technology, [1901041]. https://doi.org/10.1002/ente.201901041
Golkaram, M., Boetje, L., Dong, J., Aguilar Suarez, L., Fodor, C., Maniar, D., van Ruymbeke, E., Faraji, S., Portale, G., & Loos, K. (2019). Supramolecular Mimic for Bottlebrush Polymers in Bulk. ACS Omega, 4(15), 16481-16492. https://doi.org/10.1021/acsomega.9b02126
Terzic, I., Meereboer, N. L., Acuautla, M., Portale, G., & Loos, K. (2019). Tailored Self-Assembled Ferroelectric Polymer Nanostructures with Tunable Response. Macromolecules, 52(1), 354-364. https://doi.org/10.1021/acs.macromol.8b02131
Alvarez-Fernandez, A., Valdes-Vango, F., Ignacio Martin, J., Velez, M., Quiros, C., Hermida-Merino, D., Portale, G., Maria Alameda, J., & Garcia Alonso, F. J. (2019). Tailoring block copolymer nanoporous thin films with acetic acid as a small guest molecule. Polymer International, 68(11), 1914-1920. https://doi.org/10.1002/pi.5901

2018

Portale, G., & Torbet, J. (2018). Complex strain induced structural changes observed in fibrin assembled in human plasma. Nanoscale, 10(21), 10063-10072. https://doi.org/10.1039/c8nr00353j
Liu, J., Qiu, L., Alessandri, R., Qiu, X., Portale, G., Dong, J., Talsma, W., Ye, G., Sengrian, A. A., Souza, P. C. T., Loi, M. A., Chiechi, R. C., Marrink, S. J., Hummelen, J. C., & Koster, L. J. A. (2018). Enhancing Molecular n-Type Doping of Donor-Acceptor Copolymers by Tailoring Side Chains. Advanced materials, 30(7), [1704630]. https://doi.org/10.1002/adma.201704630
Spampinato, N., Maiz, J., Portale, G., Maglione, M., Hadziioannou, G., & Pavlopoulou, E. (2018). Enhancing the ferroelectric performance of P(VDF-co-TrFE) through modulation of crystallinity and polymorphism. Polymer, 149, 66-72. https://doi.org/10.1016/j.polymer.2018.06.072
Shao, S., Cui, Y., Duim, H., Qiu, X., Dong, J., ten Brink, G. H., Portale, G., Chiechi, R. C., Zhang, S., Hou, J., & Loi, M. A. (2018). Enhancing the Performance of the Half Tin and Half Lead Perovskite Solar Cells by Suppression of the Bulk and Interfacial Charge Recombination. Advanced materials, 30(35), [1803703]. https://doi.org/10.1002/adma.201803703
Zhang, L., Ma, C., Sun, J., Shao, B., Portale, G., Chen, D., Liu, K., & Herrmann, A. (2018). Genetically Engineered Supercharged Polypeptide Fluids: Fast and Persistent Self-Ordering Induced by Touch. Angewandte Chemie-International Edition, 57(23), 6878-6882. https://doi.org/10.1002/anie.201803169
Shao, S., Liu, J., Portale, G., Fang, H-H., Blake, G. R., ten Brink, G. H., Koster, L. J. A., & Loi, M. A. (2018). Highly Reproducible Sn-Based Hybrid Perovskite Solar Cells with 9% Efficiency. Advanced Energy Materials, 8(4), [1702019]. https://doi.org/10.1002/aenm.201702019
Liu, J., Ye, G., van der Zee, B., Dong, J., Qiu, X., Liu, Y., Portale, G., Chiechi, R. C., & Koster, L. J. A. (2018). N-Type Organic Thermoelectrics of Donor-Acceptor Copolymers: Improved Power Factor by Molecular Tailoring of the Density of States. Advanced materials, 30(44), [1804290]. https://doi.org/10.1002/adma.201804290
Povia, M., Sottmann, J., Portale, G., Knudsen, K. D., Margadonna, S., & Sartori, S. (2018). Operando SAXS/WAXS on the a-P/C as the Anode for Na-Ion Batteries. Journal of Physical Chemistry C, 122(11), 5917-5923. https://doi.org/10.1021/acs.jpcc.7b12825
Carbone, A., Gaeta, M., Romeo, A., Portale, G., Pedicini, R., Gatto, I., & Castriciano, M. A. (2018). Porphyrin/sPEEK Membranes with Improved Conductivity and Durability for PEFC Technology. ACS Applied Energy Materials, 1(4), 1664-1673. https://doi.org/10.1021/acsaem.8b00126
Liu, J., Qiu, L., Portale, G., Torabi, S., Stuart, M. C. A., Qiu, X., Koopmans, M., Chiechi, R. C., Hummelen, J. C., & Koster, L. J. A. (2018). Side-chain effects on N-type organic thermoelectrics: A case study of fullerene derivatives. Nano energy, 52, 183-191. https://doi.org/10.1016/j.nanoen.2018.07.056

2017

Mulder, D. J., Scheres, L. M. W., Dong, J., Portale, G., Broer, D. J., & Schenning, A. P. H. J. (2017). Fabrication and Postmodification of Nanoporous Liquid Crystalline Networks via Dynamic Covalent Chemistry. Chemistry of Materials, 29(16), 6601-6605. https://doi.org/10.1021/acs.chemmater.7b01334
Lazzarini, A., Groppo, E., Agostini, G., Borfecchia, E., Giannici, F., Portale, G., Longo, A., Pellegrini, R., & Lamberti, C. (2017). Formation and growth of palladium nanoparticles inside porous poly(4-vinyl-pyridine) monitored by operando techniques: The role of different reducing agents. Catalysis Today, 283, 144-150. https://doi.org/10.1016/j.cattod.2016.06.037
Dendooven, J., Ramachandran, R. K., Solano, E., Kurttepeli, M., Geerts, L., Heremans, G., Ronge, J., Minjauw, M. M., Dobbelaere, T., Devloo-Casier, K., Martens, J. A., Vantomme, A., Bals, S., Portale, G., Coati, A., & Detavernier, C. (2017). Independent tuning of size and coverage of supported Pt nanoparticles using atomic layer deposition. Nature Communications, 8, [1074]. https://doi.org/10.1038/s41467-017-01140-z
Zhang, L., Maity, S., Liu, K., Liu, Q., Göstl, R., Portale, G., Roos, W. H., & Herrmann, A. (2017). Nematic DNA Thermotropic Liquid Crystals with Photoresponsive Mechanical Properties. Small, 13(34), 1701207. [1701207]. https://doi.org/10.1002/smll.201701207
Liu, J., Qiu, L., Portale, G., Koopmans, M., Ten Brink, G., Hummelen, J. C., & Koster, L. J. A. (2017). N-Type Organic Thermoelectrics: Improved Power Factor by Tailoring Host-Dopant Miscibility. Advanced materials, 29(36), [1701641]. https://doi.org/10.1002/adma.201701641
Longo, A., Mulder, D-J., van Kuringen, H. P. C., Hermida-Merino, D., Banerjee, D., Dasgupta, D., Shishmanova, I. K., Spoelstra, A. B., Broer, D. J., Schenning, A. P. H. J., & Portale, G. (2017). On the Dimensional Control of 2D Hybrid Nanomaterials. Chemistry, 23(51), 12534-12541. https://doi.org/10.1002/chem.201701493
Portale, G., Troisi, E. M., Peters, G. W. M., & Bras, W. (2017). Real-Time Fast Structuring of Polymers Using Synchrotron WAXD/SAXS Techniques. In F. Auriemma, GC. Alfonso, & C. DeRosa (Eds.), Polymer Crystallization II. Advances in Polymer Science (pp. 127-165). (Advances in Polymer Science; Vol. 277). Springer-Verlag Berlin Heidelberg. https://doi.org/10.1007/12_2015_331
van Franeker, J. J., Hermida-Merino, D., Gommes, C., Arapov, K., Michels, J. J., Janssen, R. A. J., & Portale, G. (2017). Sub-Micrometer Structure Formation during Spin Coating Revealed by Time-Resolved In Situ Laser and X-Ray Scattering. Advanced Functional Materials, 27(46), [1702516]. https://doi.org/10.1002/adfm.201702516
Balko, J., Portale, G., Lohwasser, R. H., Thelakkat, M., & Thurn-Albrecht, T. (2017). Surface induced orientation and vertically layered morphology in thin films of poly(3-hexylthiophene) crystallized from the melt. Journal of materials research, 32(10), 1957-1968. https://doi.org/10.1557/jmr.2017.107
Aissou, K., Mumtaz, M., Portale, G., Brochon, C., Cloutet, E., Fleury, G., & Hadziioannou, G. (2017). Templated Sub-100-nm-Thick Double-Gyroid Structure from Si-Containing Block Copolymer Thin Films. Small, 13(20), [1603777]. https://doi.org/10.1002/smll.201603777

2016

Munoz-Noval, A., Fukami, K., Koyama, A., Gallach, D., Hermida-Merino, D., Portale, G., Kitada, A., Murase, K., Abe, T., Hayakawa, S., & Sakka, T. (2016). Accelerated growth from amorphous clusters to metallic nanoparticles observed in electrochemical deposition of platinum within nanopores of porous silicon. Electrochemistry communications, 71, 9-12. https://doi.org/10.1016/j.elecom.2016.07.013
Aissou, K., Mumtaz, M., Usluer, Ö., Pécastaings, G., Portale, G., Fleury, G., Cloutet, E., & Hadziioannou, G. (2016). Anisotropic Lithium Ion Conductivity in Single-Ion Diblock Copolymer Electrolyte Thin Films. Macromolecular Rapid Communications, 37(3), 221-226. https://doi.org/10.1002/marc.201500562
Aissou, K., Kwon, W., Mumtaz, M., Antoine, S., Maret, M., Portale, G., Fleury, G., & Hadziioannou, G. (2016). Archimedean Tilings and Hierarchical Lamellar Morphology Formed by Semicrystalline Miktoarm Star Terpolymer Thin Films. Acs Nano, 10(4), 4055-4061. https://doi.org/10.1021/acsnano.5b06728
Serbenta, A., Kozlov, O. V., Portale, G., van Loosdrecht, P. H. M., & Pshenichnikov, M. S. (2016). Bulk heterojunction morphology of polymer: fullerene blends revealed by ultrafast spectroscopy. Scientific Reports, 6, [36236]. https://doi.org/10.1038/srep36236
Jaspers, M., Pape, A. C. H., Voets, I. K., Rowan, A. E., Portale, G., & Kouwer, P. H. J. (2016). Bundle Formation in Biomimetic Hydrogels. Biomacromolecules, 17(8), 2642-2649. https://doi.org/10.1021/acs.biomac.6b00703
Jennings, J., Bassett, S. P., Hermida-Merino, D., Portale, G., Bras, W., Knight, L., Titman, J. J., Higuchi, T., Jinnai, H., & Howdle, S. M. (2016). How does dense phase CO2 influence the phase behaviour of block copolymers synthesised by dispersion polymerisation? Polymer Chemistry, 7(4), 905-916. https://doi.org/10.1039/c5py01823d
Wilsens, C. H. R. M., Pepels, M. P. F., Spoelstra, A. B., Portale, G., Auhl, D., Deshmukh, Y. S., & Harings, J. A. W. (2016). Improving Stiffness, Strength, and Toughness of Poly(omega-pentadecalactone) Fibers through in Situ Reinforcement with a Vanillic Acid-Based Thermotropic Liquid Crystalline Polyester. Macromolecules, 49(6), 2228-2237. https://doi.org/10.1021/acs.macromol.5b02419
Deshmukh, Y. S., Wilsens, C. H. R. M., Leone, N., Portale, G., Harings, J. A. W., & Rastogi, S. (2016). Melt-Miscible Oxalamide Based Nucleating Agents and Their Nucleation Efficiency in Isotactic Polypropylene. Industrial and Engineering Chemistry Research, 55(45), 11756-11766. https://doi.org/10.1021/acs.iecr.6b03120
Dendooven, J., Solano, E., Minjauw, M. M., Van de Kerckhove, K., Coati, A., Fonda, E., Portale, G., Garreau, Y., & Detavernier, C. (2016). Mobile setup for synchrotron based in situ characterization during thermal and plasma-enhanced atomic layer deposition. Review of Scientific Instruments, 87(11), [113905]. https://doi.org/10.1063/1.4967711
Vita, F., Hegde, M., Portale, G., Bras, W., Ferrero, C., Samulski, E. T., Francescangeli, O., & Dingemans, T. (2016). Molecular ordering in the high-temperature nematic phase of an all-aromatic liquid crystal. Soft Matter, 12(8), 2309-2314. https://doi.org/10.1039/c5sm02738a
Last modified:13 October 2015 3.45 p.m.