dr. P. (Patrizio) Raffa
Assistant Professor in Polymeric Products

E-mail:
p.raffa rug.nl
Research
Research units:
Postal address:
Nijenborgh4
9747 AG
Groningen
Netherlands
Phone: +31 50 363 4465Fax: +31 50 363 4479
1 - 46 out of 46Page size: 50
- 2020
- Boulif, N., Sebakhy, K. O., Joosten, H., & Raffa, P. (2020). Design and synthesis of novel di‐ and triblock amphiphilic polyelectrolytes: Improving salt‐induced viscosity reduction of water solutions for potential application in enhanced oil recovery. Journal of Applied Polymer Science, [50366]. https://doi.org/10.1002/app.50366
- Migliore, N., Zijlstra, D. S., Kooten, T. G. V., Deuss, P. J., & Raffa, P. (2020). Amphiphilic Copolymers Derived from Butanosolv Lignin and Acrylamide: Synthesis, Properties in Water Solution, and Potential Applications. ACS Applied Polymer Materials, (12), 5705-5715. https://doi.org/10.1021/acsapm.0c01006
- Raffa, P., Peixoto, C. S. P., da Costa, P. F. A., Polgar, L. M., Machado, A. V., Hough, P., & van Duin, M. (2020). Optimization of hybrid oil/water-swelling ethylene/propylene/diene monomer compounds. Journal of Applied Polymer Science, 137(48), [49579]. https://doi.org/10.1002/app.49579
- Araya-Hermosilla, E., Moreno-Villoslada, I., Araya-Hermosilla, R., Flores, M. E., Raffa, P., Biver, T., Pucci, A., Picchioni, F., & Mattoli, V. (2020). pH-Responsive Polyketone/5,10,15,20-Tetrakis-(Sulfonatophenyl)Porphyrin Supramolecular Submicron Colloidal Structures. Polymers, 12(9), 1-18. [2017]. https://doi.org/10.3390/polym12092017
- 2019
- Araya-Hermosilla, E., Abbing, M. R., Catalan-Toledo, J., Oyarzun-Ampuero, F., Pucci, A., Raffa, P., Picchioni, F., & Moreno-Villoslada, I. (2019). Synthesis of tuneable amphiphilic-modified polyketone polymers, their complexes with 5,10,15,20-tetrakis-(4-sulfonatophenyl)porphyrin, and their role in the photooxidation of 1,3,5-triphenylformazan confined in polymeric nanoparticles. Polymer, 167, 215-223. https://doi.org/10.1016/j.polymer.2019.01.079
- Di Sacco, F., Pucci, A., & Raffa, P. (2019). Versatile multi-functional block copolymers made by atom transfer radical polymerization and post-synthetic modification: Switching from volatile organic compound sensors to polymeric surfactants for water rheology control via hydrolysis. Nanomaterials, 9(3), [458]. https://doi.org/10.3390/nano9030458
- Polgar, L. M., Fallani, F., Cuijpers, J., Raffa, P., Broekhuis, A., van Duin, M., & Picchioni, F. (2019). Water-swellable elastomers: synthesis, properties and applications. Reviews in Chemical Engineering, 35(1), 45-72. https://doi.org/10.1515/revce-2017-0052
- 2018
- Klemm, B., Picchioni, F., van Mastrigt, F., & Raffa, P. (2018). Starlike Branched Polyacrylamides by RAFT Polymerization-Part I: Synthesis and Characterization. ACS Omega, 3(12), 18762-18770. https://doi.org/10.1021/acsomega.8b03178
- Araya-Hermosilla, R., Pucci, A., Raffa, P., Santosa, D., Pescarmona, P. P., Gengler, R. Y. N., Rudolf, P., Moreno-Villoslada, I., & Picchioni, F. (2018). Electrically-Responsive Reversible Polyketone/MWCNT Network through Diels-Alder Chemistry. Polymers, 10(10), [1076]. https://doi.org/10.3390/polym10101076
- Klemm, B., Picchioni, F., Raffa, P., & van Mastrigt, F. (2018). Star-Like Branched Polyacrylamides by RAFT polymerization, Part II: Performance Evaluation in Enhanced Oil Recovery (EOR). Industrial & Engineering Chemistry Research, 57(27), 8835-8844. https://doi.org/10.1021/acs.iecr.7b03368
- Migliore, N., Polgar, L. M., Araya-Hermosilla, R., Picchioni, F., Raffa, P., & Pucci, A. (2018). Effect of the Polyketone Aromatic Pendent Groups on the Electrical Conductivity of the Derived MWCNTs-Based Nanocomposites. Polymers, 10(6), [618]. https://doi.org/10.3390/polym10060618
- Noordergraaf, I., Fourie, T. K., & Raffa, P. (2018). Free-Radical Graft Polymerization onto Starch as a Tool to Tune Properties in Relation to Potential Applications: A Review. Processes, 6(4), 31. https://doi.org/10.3390/pr6040031
- Araya-Hermosilla, E., Catalán-Toledo, J., Muñoz-Suescun, F., Oyarzun-Ampuero, F., Raffa, P., Polgar, L. M., Picchioni, F., & Moreno-Villoslada, I. (2018). Totally Organic Redox-Active pH-Sensitive Nanoparticles Stabilized by Amphiphilic Aromatic Polyketones. The Journal of Physical Chemistry. B: Materials, Surfaces, Interfaces, & Biophysical, 122(5), 1747-1755. https://doi.org/10.1021/acs.jpcb.7b11254
- Polgar, L. M., Criscitiello, F., van Essen, M., Araya-Hermosilla, R., Migliore, N., Lenti, M., Raffa, P., Picchioni, F., & Pucci, A. (2018). Thermoreversibly Cross-Linked EPM Rubber Nanocomposites with Carbon Nanotubes. Nanomaterials (Basel, Switzerland), 8(2), [58]. https://doi.org/10.3390/nano8020058
- 2017
- Polgar, L. M., Hagting, E., Raffa, P., Mauri, M., Simonutti, R., Picchioni, F., & van Duin, M. (2017). Effect of Rubber Polarity on Cluster Formation in Rubbers Cross-Linked with Diels-Alder Chemistry. Macromolecules, 50(22), 8955-8964. https://doi.org/10.1021/acs.macromol.7b01541
- Meijerink, M., van Mastrigt, F., Franken, L. E., Stuart, M. C. A., Picchioni, F., & Raffa, P. (2017). Triblock copolymers of styrene and sodium methacrylate as smart materials: synthesis and rheological characterization. Pure and Applied Chemistry, 89(11), 1641-1658. https://doi.org/10.1515/pac-2016-1021
- 2016
- Raffa, P., Broekhuis, A. A., & Picchioni, F. (2016). Polymeric surfactants for enhanced oil recovery: A review. Journal of Petroleum Science and Engineering, 145, 723-733. https://doi.org/10.1016/j.petrol.2016.07.007
- Araya-Hermosilla, R., Lima, G. M. R., Raffa, P., Fortunato, G., Pucci, A., Flores, M. E., Moreno-Villoslada, I., Broekhuis, A. A., & Picchioni, F. (2016). Intrinsic self-healing thermoset through covalent and hydrogen bonding interactions. European Polymer Journal, 81, 186-197. https://doi.org/10.1016/j.eurpolymj.2016.06.004
- Araya-Hermosilla, R., Fortunato, G., Pucci, A., Raffa, P., Polgar, L., Broekhuis, A. A., Pourhossein, P., Lima, G. M. R., Beljaars, M., & Picchioni, F. (2016). Thermally reversible rubber-toughened thermoset networks via Diels-Alder chemistry. European Polymer Journal, 74, 229-240. https://doi.org/10.1016/j.eurpolymj.2015.11.020
- Araya-Hermosilla, R., Pucci, A., Araya-Hermosilla, E., Pescarmona, P. P., Raffa, P., Polgar, L. M., Moreno-Villoslada, I., Flores, M., Fortunato, G., Broekhuis, A. A., & Picchioni, F. (2016). An easy synthetic way to exfoliate and stabilize MWCNTs in a thermoplastic pyrrole-containing matrix assisted by hydrogen bonds. RSC Advances, 6(89), 85829-85837. https://doi.org/10.1039/c6ra11054a
- 2015
- Raffa, P., Wever, D. A. Z., Picchioni, F., & Broekhuis, A. A. (2015). Polymeric Surfactants: Synthesis, Properties, and Links to Applications. Chemical reviews, 115(16), 8504-8563. https://doi.org/10.1021/cr500129h
- 2014
- Raffa, P., Coltelli, M-B., & Castelvetro, V. (2014). Expanding the Application Field of Post-Consumer Poly(ethylene terephthalate) Through Structural Modification by Reactive Blending. Journal of Applied Polymer Science, 131(19), [40881]. https://doi.org/10.1002/app.40881
- Raffa, P., Stuart, M. C. A., Broekhuis, A. A., & Picchioni, F. (2014). The effect of hydrophilic and hydrophobic block length on the rheology of amphiphilic diblock Polystyrene-b-Poly(sodium methacrylate) copolymers prepared by ATRP. Journal of Colloid and Interface Science, 428, 152-161. https://doi.org/10.1016/j.jcis.2014.04.047
- Raffa, P. (2014). Polystyrene-Based Amphiphilic Block Copolymers: Synthesis, Properties and Application. In C. Lynwood (Ed.), Polystyrene: Synthesis, Characteristics and Applications (pp. 31-52). Nova Science Publishers.
- 2013
- Raffa, P., Brandenburg, P., Wever, D. A. Z., Broekhuis, A. A., & Picchioni, F. (2013). Polystyrene-Poly(sodium methacrylate) Amphiphilic Block Copolymers by ATRP: Effect of Structure, pH, and Ionic Strength on Rheology of Aqueous Solutions. Macromolecules, 46(17), 7106-7111. https://doi.org/10.1021/ma401453j
- 2012
- Wever, D. A. Z., Raffa, P., Picchioni, F., & Broekhuis, A. A. (2012). Acrylamide Homopolymers and Acrylamide-N-Isopropylacrylamide Block Copolymers by Atomic Transfer Radical Polymerization in Water. Macromolecules, 45(10), 4040-4045. https://doi.org/10.1021/ma3006125
- Raffa, P., Coltelli, M-B., Savi, S., Bianchi, S., & Castelvetro, V. (2012). Chain extension and branching of poly(ethylene terephthalate) (PET) with di- and multifunctional epoxy or isocyanate additives: An experimental and modelling study. Reactive & Functional Polymers, 72(1), 50-60. https://doi.org/10.1016/j.reactfunctpolym.2011.10.007
- Bozzini, B., Tondo, E., Raffa, P., & Boniardi, M. (2012). Electrodeposition of Y2O3-Au composite coatings for SOFC interconnects: in situ monitoring of film growth by surface enhanced Raman spectroscopy. Transactions of the Institute of Metal Finishing, 90(1), 30-37. https://doi.org/10.1179/174591911X13222243458060
- 2011
- Bozzini, B., Busson, B., Humbert, C., Mele, C., Raffa, P., & Tadjeddine, A. (2011). Investigation of Au electrodeposition from [BMP][TFSA] room-temperature ionic liquid containing K[Au(CN)(2)] by in situ two-dimensional sum frequency generation spectroscopy. Journal of Electroanalytical Chemistry, 661(1), 20-24. https://doi.org/10.1016/j.jelechem.2011.07.004
- Evangelisti, C., Raffa, P., Uccello-Barretta, G., Vitulli, G., Bertinetti, L., & Martra, G. (2011). A Way to Decylamine-Stabilized Gold Nanoparticles of Tailored Sizes Tuning Their Growth in Solution. Journal of Nanoscience and Nanotechnology, 11(3), 2226-2231. https://doi.org/10.1166/jnn.2011.3730
- 2009
- Uccello-Barretta, G., Evangelisti, C., Raffa, P., Balzano, F., Nazzi, S., Martra, G., Vitulli, G., & Salvadori, P. (2009). The control of the growth of Pt clusters in solution: A way to prepare Pt particles of tailored size. Journal of Organometallic Chemistry, 694(12), 1813-1817. https://doi.org/10.1016/j.jorganchem.2009.01.010
- 2008
- Raffa, P., Evangelisti, C., Vitulli, G., & Salvadori, P. (2008). First examples of gold nanoparticles catalyzed silane alcoholysis and silylative pinacol coupling of carbonyl compounds. Tetrahedron Letters, 49(20), 3221-3224. https://doi.org/10.1016/j.tetlet.2008.03.092
- Uccello-Barretta, G., Balzano, F., Evangelisti, C., Raffa, P., Mandoli, A., Nazzi, S., & Vitulli, G. (2008). A new platinum vapor-derived highly efficient hydrosilylation catalyst: NMR structural investigation. Journal of Organometallic Chemistry, 693(7), 1276-1282. https://doi.org/10.1016/j.jorganchem.2008.01.024
- Evangelisti, C., Raffa, P., Balzano, F., Barretta, G. U., Vitulli, G., & Salvadori, P. (2008). Size-controlled synthesis and NMR characterization of mesitylene-vinylsiloxanes stabilized Pt nanoparticles in solution. Journal of Nanoscience and Nanotechnology, 8(4), 2096-2101. https://doi.org/10.1166/jnn.2008.061
- 2006
- Aronica, LA., Raffa, P., Valentini, G., Caporusso, AM., & Salvadori, P. (2006). Silylformylation - Fluoride-assisted aryl migration of acetylenic derivatives in a versatile approach to the synthesis of polyfunctionalised compounds. European Journal of Organic Chemistry, (8), 1845-1851. https://doi.org/10.1002/ejoc.200500883
- Aronica, LA., Raffa, P., Valentini, G., Caporusso, AM., & Salvadori, P. (2006). Silylformylation-desilylation of propargyl amides: synthesis of alpha,beta-unsaturated aldehydes. Tetrahedron Letters, 47(4), 527-530. https://doi.org/10.1016/j.tetlet.2005.11.054
- 2003
- Aronica, LA., Raffa, P., Caporusso, AM., & Salvadori, P. (2003). Fluoride-promoted rearrangement of organo silicon compounds: A new synthesis of 2-(arylmethyl)aldehydes from 1-alkynes. Journal of Organic Chemistry, 68(24), 9292-9298. https://doi.org/10.1021/jo0351062
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