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Lecture Eric Goethals


18 juni 2010 FWN-Building 5118.-152, Nijenborgh 4, 9747 AG, Groningen
Speaker: Prof. Em. Eric Goethals
Affiliation: University of Ghent, Belgium
Title: Carbocationic polymerizations: how the living systems were developed
Date: Fri Jun 18, 2010
Start: 11.00
Location: FWN-Building 5118.-152
Host: T. Loontjens
Telephone: +31 50 363 4512


Until the eighties, it was generally accepted that carbocationic polymerizations were intrinsically “uncontrollable” due to the extreme reactivity of the propagating species (carbenium ions). For ex. the rate constant of propagation for the cationic polymerization of isobutene at -90°C is estimated to be 108 L/mol.sec. In this presentation, the slow but steady progress in controllability of cationic polymerizations, eventually leading to living systems will be described. Selected examples of the use of these polymerizations for the synthesis of well defined polymer structures will be given.

Laatst gewijzigd:22 oktober 2012 14:31