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Lecture Graham J. Bodwell


17 juli 2009 FWN-Building 5118.-156, Nijenborgh 4, 9747 AG, Groningen
Speaker: Dr. Graham J. Bodwell
Affiliation: Department of Chemistry, Memorial University St. John's, Canada
Title: The VID reaction in the synthesis of substructures and segments of single-walled carbon nanotubes
Date: Fri Jul 17, 2009
Start: 11.00
Location: FWN-Building 5118.-156
Host: A. Herrmann
Telephone: +31 50 363 6318


The valence isomerization / dehydrogenation (VID) reaction of [2.2]metacyclophane-1,9-dienes has proved to be a very powerful method for the formation of (2,7)pyrenophanes having nonplanar pyrene systems.  Even severely distorted pyrenes can be synthesized under relatively mild conditions.  More recently, we have working to extend this methodology to the synthesis of much larger cyclophanes, the aromatic systems of which map onto the surfaces of armachair single-walled carbon nanotubes.  The synthesis and structural features of 1,1,8,8-tetramethyl[8](2,11)teropyrenophane will be presented along with progress toward the synthesis of complete aromatic belts.

Laatst gewijzigd:22 oktober 2012 14:30