Publication

Valorization strategies for pyrolytic lignin

Bernardes Figueiredo, M., 2020, [Groningen]: University of Groningen. 275 p.

Research output: ThesisThesis fully internal (DIV)

Copy link to clipboard

Documents

  • Title and contents

    Final publisher's version, 3.44 MB, PDF document

  • Chapter 1

    Final publisher's version, 3.42 MB, PDF document

  • Chapter 2

    Final publisher's version, 4.82 MB, PDF document

    Embargo ends: 17/01/2021

    Request copy

  • Chapter 3

    Final publisher's version, 5.21 MB, PDF document

  • Chapter 4

    Final publisher's version, 6.42 MB, PDF document

    Embargo ends: 17/01/2021

    Request copy

  • Chapter 5

    Final publisher's version, 5.03 MB, PDF document

  • Chapter 6

    Final publisher's version, 4.51 MB, PDF document

  • Chapter 7

    Final publisher's version, 4.85 MB, PDF document

  • Chapter 8

    Final publisher's version, 5.15 MB, PDF document

    Embargo ends: 17/01/2021

    Request copy

  • Addendum

    Final publisher's version, 1.71 MB, PDF document

  • Complete thesis

    Final publisher's version, 23.8 MB, PDF document

    Embargo ends: 17/01/2021

    Request copy

  • Propositions

    Final publisher's version, 33.1 KB, PDF document

DOI

Pressing environmental concerns have encouraged research towards the development of sustainable alternatives for the current petroleum-based industry. In this context, lignocellulosic biomass (plant matter) is expected to play an important role in decarbonizing the economy due to its high availability, renewable character and rich chemical structure. Lignocellulose is mainly composed of carbohydrates (cellulose and hemicellulose fractions) and aromatic biopolymers (lignin fraction). Through the well-established pyrolysis technology, it is thermally deconstructed into a liquid that can be fractionated into a water-soluble sugar phase and a lignin phase (pyrolytic lignin). While biobased sugars are used in various processes, lignin has been overlooked due to its complex structural features and treated as residue that is burned for low-value energy generation. Nonetheless, it has great potential as a source of biofuels and biobased chemicals with a range of applications. In this thesis, reductive (catalytic, using hydrogen) and oxidative (non-catalytic, using ozone) strategies for pyrolytic lignin depolymerization into value-added products were experimentally evaluated. Studies include the detailed characterization of a typical pyrolytic lignin structure followed by catalyst screenings for reductive upgrading, as well as ozonation in batch and continuous set-ups. This led to the development of a two-step oxidative-reductive system for improved depolymerization to low molecular weight biobased chemicals. Furthermore, the biomass source influence was evaluated, as well as extension of novel strategies to other lignin types. The promising results reported will contribute to the development of biorefineries, whose realization ultimately depends on maximum value extraction from the lignin fraction.
Original languageEnglish
QualificationDoctor of Philosophy
Awarding Institution
Supervisors/Advisors
Award date17-Jan-2020
Place of Publication[Groningen]
Publisher
Print ISBNs978-94-034-2277-0
Electronic ISBNs978-94-034-2278-7
Publication statusPublished - 2020

Download statistics

No data available

ID: 111703614