Two new types of pi-conjugation between a fullerene sphere and an addendKooistra, F. B., Leuning, T. M., Martinez, E. M. & Hummelen, J. C., 2010, In : Chemical Communications. 46, 12, p. 2097-2099 3 p.
Research output: Contribution to journal › Article › Academic › peer-review
Diazirine addition reactions to C(60), followed by an HCl elimination step, yielded [6,6] and [5,6] sp(2) carbon bridged fullerenes. The [5,6] adducts (alkylidenehomofullerenes) are the first examples of fullerene structures where the addend is attached to the fullerene cage in a true, albeit highly bent, alternating single-double bond fashion.
|Number of pages||3|
|Publication status||Published - 2010|
- SOLAR-CELLS, DIAZIRINES, METHANOFULLERENE, DECOMPOSITION, PHOTOLYSIS, ACCEPTOR, POLYMER, C-60