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Two new types of pi-conjugation between a fullerene sphere and an addend

Kooistra, F. B., Leuning, T. M., Martinez, E. M. & Hummelen, J. C., 2010, In : Chemical Communications. 46, 12, p. 2097-2099 3 p.

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DOI

Diazirine addition reactions to C(60), followed by an HCl elimination step, yielded [6,6] and [5,6] sp(2) carbon bridged fullerenes. The [5,6] adducts (alkylidenehomofullerenes) are the first examples of fullerene structures where the addend is attached to the fullerene cage in a true, albeit highly bent, alternating single-double bond fashion.

Original languageEnglish
Pages (from-to)2097-2099
Number of pages3
JournalChemical Communications
Volume46
Issue number12
Publication statusPublished - 2010

    Keywords

  • SOLAR-CELLS, DIAZIRINES, METHANOFULLERENE, DECOMPOSITION, PHOTOLYSIS, ACCEPTOR, POLYMER, C-60

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