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Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido Complex

Padamati, S. K., Angelone, D., Draksharapu, A., Primi, G., Martin, D. J., Tromp, M., Swart, M. & Browne, W. R., 28-Jun-2017, In : Journal of the American Chemical Society. 139, 25, p. 8718-8724 7 p.

Research output: Contribution to journalArticleAcademicpeer-review

A reactive high-valent dinuclear nickel(IV) oxido bridged complex is reported that can be formed at room temperature by reaction of [(L)2Ni(II)2(μ-X)3]X (X = Cl or Br) with NaOCl in methanol or acetonitrile (where L = 1,4,7-trimethyl-1,4,7-triazacyclononane). The unusual Ni(IV) oxido species is stabilized within a dinuclear tris-μ-oxido-bridged structure as [(L)2Ni(IV)2(μ-O)3]2+. Its structure and its reactivity with organic substrates are demonstrated through a combination of UV-vis absorption, resonance Raman, 1H NMR, EPR, and X-ray absorption (near-edge) spectroscopy, ESI mass spectrometry, and DFT methods. The identification of a Ni(IV)-O species opens opportunities to control the reactivity of NaOCl for selective oxidations.

Original languageEnglish
Pages (from-to)8718-8724
Number of pages7
JournalJournal of the American Chemical Society
Volume139
Issue number25
Publication statusPublished - 28-Jun-2017

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