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The diphenyl-amino radical dimer

Wiersma, D. A. & Kommandeur, J., 1967, In : Molecular Physics. 13, 3, 11 p.

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  • Douwe A. Wiersma
  • Jan Kommandeur
E.S.R. measurements on the photodissociation-products of tetraphenylhydrazine in rigid solution at 77°K indicate that the principal product of this dissociation is the dimer of the diphenyl amino radical. This assignment is confirmed by a measurement of a half-field signal and computer simulation of the E.S.R. spectra in rigid solution. A long wavelength charge-transfer band arises through the interaction of the two diphenyl amino radicals. An SCMO calculation is presented, which gives a theoretical background to the latter assignment.
Original languageEnglish
Number of pages11
JournalMolecular Physics
Volume13
Issue number3
Publication statusPublished - 1967

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