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The application of water-soluble ruthenium catalysts for the hydrogenation of the dichloromethane soluble fraction of fast pyrolysis oil and related model compounds in a two phase aqueous-organic system

Mahfud, F. H., Bussemaker, S., Kooi, B. J., ten Brink, G. & Heeres, H. J., 16-Nov-2007, In : Journal of Molecular Catalysis A-Chemical. 277, 1-2, p. 127-136 10 p.

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DOI

The hydrogenation of a dichloromethane soluble fraction of flash pyrolysis oil (bio-oil, BO), obtained by treatment of BO with a water–dichloromethane solvent mixture, was investigated using a water-soluble homogeneous ruthenium catalyst (RuCl3·3H2O/tris(m-sulfonatophenyl)phosphine, TPPTS). The catalyst is active at mild conditions (
Original languageEnglish
Pages (from-to)127-136
Number of pages10
JournalJournal of Molecular Catalysis A-Chemical
Volume277
Issue number1-2
Publication statusPublished - 16-Nov-2007

    Keywords

  • hydrogenation, biphasic catalysis, RUCl3, tris(m-sulfonatophenyl)phosphine (TPPTS), homogeneous catalyst, hydrodeoxygenation, flash pyrolysis oil, SELECTIVE HYDROGENATION, SULFIDED COMO/GAMMA-AL2O3, HOMOGENEOUS CATALYSIS, ALPHA,BETA-UNSATURATED ALDEHYDES, NIMO/GAMMA-AL2O3 CATALYSTS, ORGANOMETALLIC CATALYSIS, FORESTRY RESIDUE, FLASH PYROLYSIS, GUAIACYL GROUPS, COMPLEXES

ID: 1647496