Publication

Synthesis of fatty acid starch esters in supercritical carbon dioxide

Muljana, H., van der Knoop, S., Keijzer, D., Picchioni, F., Janssen, L. P. B. M. & Heeres, H. J., 5-Sep-2010, In : Carbohydrate Polymers. 82, 2, p. 346-354 9 p.

Research output: Contribution to journalArticleAcademicpeer-review

APA

Muljana, H., van der Knoop, S., Keijzer, D., Picchioni, F., Janssen, L. P. B. M., & Heeres, H. J. (2010). Synthesis of fatty acid starch esters in supercritical carbon dioxide. Carbohydrate Polymers, 82(2), 346-354. https://doi.org/10.1016/j.carbpol.2010.04.067

Author

Muljana, Henky ; van der Knoop, Sjoerd ; Keijzer, Danielle ; Picchioni, Francesco ; Janssen, Leon P. B. M. ; Heeres, Hero J. / Synthesis of fatty acid starch esters in supercritical carbon dioxide. In: Carbohydrate Polymers. 2010 ; Vol. 82, No. 2. pp. 346-354.

Harvard

Muljana, H, van der Knoop, S, Keijzer, D, Picchioni, F, Janssen, LPBM & Heeres, HJ 2010, 'Synthesis of fatty acid starch esters in supercritical carbon dioxide', Carbohydrate Polymers, vol. 82, no. 2, pp. 346-354. https://doi.org/10.1016/j.carbpol.2010.04.067

Standard

Synthesis of fatty acid starch esters in supercritical carbon dioxide. / Muljana, Henky; van der Knoop, Sjoerd; Keijzer, Danielle; Picchioni, Francesco; Janssen, Leon P. B. M.; Heeres, Hero J.

In: Carbohydrate Polymers, Vol. 82, No. 2, 05.09.2010, p. 346-354.

Research output: Contribution to journalArticleAcademicpeer-review

Vancouver

Muljana H, van der Knoop S, Keijzer D, Picchioni F, Janssen LPBM, Heeres HJ. Synthesis of fatty acid starch esters in supercritical carbon dioxide. Carbohydrate Polymers. 2010 Sep 5;82(2):346-354. https://doi.org/10.1016/j.carbpol.2010.04.067


BibTeX

@article{6780053eccd9437291bcc90a1a02f3b1,
title = "Synthesis of fatty acid starch esters in supercritical carbon dioxide",
abstract = "This manuscript describes an exploratory study on the synthesis of fatty acid/potato starch esters using supercritical carbon dioxide (scCO(2)) as the solvent. The effects of process variables such as pressure (6-25 MPa), temperature (120-150 degrees C) and various basic catalysts and fatty acid derivatives (methyl- and vinyl esters and anhydrides) on the degree of substitution (DS) were explored in a batch reactor set-up. Products with a broad range of DS values (0.01-0.31) were obtained, the actual values depending on process conditions, type of catalyst and the fatty acid reagent. The combination of K(2)CO(3) and vinyl laurate gave the highest DS values (DS = 0.31 at 150 degrees C, 8 MPa). The introduction of the fatty acid chains has a profound effect on product properties like hydrophobicity and thermal behavior. (C) 2010 Elsevier Ltd. All rights reserved.",
keywords = "Fatty acid starch esters, Potato starch, Starch laurate, Supercritical CO(2), PRESSURE PHASE-EQUILIBRIA, POTATO STARCH, CHEMICAL-MODIFICATION, THERMAL-PROPERTIES, ACETIC-ANHYDRIDE, METHYL PALMITATE, ORGANIC-SOLVENT, VINYL-ACETATE, CORN STARCH, PART 2",
author = "Henky Muljana and {van der Knoop}, Sjoerd and Danielle Keijzer and Francesco Picchioni and Janssen, {Leon P. B. M.} and Heeres, {Hero J.}",
year = "2010",
month = sep,
day = "5",
doi = "10.1016/j.carbpol.2010.04.067",
language = "English",
volume = "82",
pages = "346--354",
journal = "Carbohydrate Polymers",
issn = "0144-8617",
publisher = "ELSEVIER SCI LTD",
number = "2",

}

RIS

TY - JOUR

T1 - Synthesis of fatty acid starch esters in supercritical carbon dioxide

AU - Muljana, Henky

AU - van der Knoop, Sjoerd

AU - Keijzer, Danielle

AU - Picchioni, Francesco

AU - Janssen, Leon P. B. M.

AU - Heeres, Hero J.

PY - 2010/9/5

Y1 - 2010/9/5

N2 - This manuscript describes an exploratory study on the synthesis of fatty acid/potato starch esters using supercritical carbon dioxide (scCO(2)) as the solvent. The effects of process variables such as pressure (6-25 MPa), temperature (120-150 degrees C) and various basic catalysts and fatty acid derivatives (methyl- and vinyl esters and anhydrides) on the degree of substitution (DS) were explored in a batch reactor set-up. Products with a broad range of DS values (0.01-0.31) were obtained, the actual values depending on process conditions, type of catalyst and the fatty acid reagent. The combination of K(2)CO(3) and vinyl laurate gave the highest DS values (DS = 0.31 at 150 degrees C, 8 MPa). The introduction of the fatty acid chains has a profound effect on product properties like hydrophobicity and thermal behavior. (C) 2010 Elsevier Ltd. All rights reserved.

AB - This manuscript describes an exploratory study on the synthesis of fatty acid/potato starch esters using supercritical carbon dioxide (scCO(2)) as the solvent. The effects of process variables such as pressure (6-25 MPa), temperature (120-150 degrees C) and various basic catalysts and fatty acid derivatives (methyl- and vinyl esters and anhydrides) on the degree of substitution (DS) were explored in a batch reactor set-up. Products with a broad range of DS values (0.01-0.31) were obtained, the actual values depending on process conditions, type of catalyst and the fatty acid reagent. The combination of K(2)CO(3) and vinyl laurate gave the highest DS values (DS = 0.31 at 150 degrees C, 8 MPa). The introduction of the fatty acid chains has a profound effect on product properties like hydrophobicity and thermal behavior. (C) 2010 Elsevier Ltd. All rights reserved.

KW - Fatty acid starch esters

KW - Potato starch

KW - Starch laurate

KW - Supercritical CO(2)

KW - PRESSURE PHASE-EQUILIBRIA

KW - POTATO STARCH

KW - CHEMICAL-MODIFICATION

KW - THERMAL-PROPERTIES

KW - ACETIC-ANHYDRIDE

KW - METHYL PALMITATE

KW - ORGANIC-SOLVENT

KW - VINYL-ACETATE

KW - CORN STARCH

KW - PART 2

U2 - 10.1016/j.carbpol.2010.04.067

DO - 10.1016/j.carbpol.2010.04.067

M3 - Article

VL - 82

SP - 346

EP - 354

JO - Carbohydrate Polymers

JF - Carbohydrate Polymers

SN - 0144-8617

IS - 2

ER -

ID: 5134284