Publication

Supramolecular Route to Well-Ordered Metal Nanofoams

Vukovic, I., Punzhin, S., Vukovic, Z., Onck, P., De Hosson, J. T. M., ten Brinke, G. & Loos, K., Aug-2011, In : Acs Nano. 5, 8, p. 6339-6348 10 p.

Research output: Contribution to journalArticleAcademicpeer-review

APA

Vukovic, I., Punzhin, S., Vukovic, Z., Onck, P., De Hosson, J. T. M., ten Brinke, G., & Loos, K. (2011). Supramolecular Route to Well-Ordered Metal Nanofoams. Acs Nano, 5(8), 6339-6348. https://doi.org/10.1021/nn201421y

Author

Vukovic, Ivana ; Punzhin, Sergey ; Vukovic, Zorica ; Onck, Patrick ; De Hosson, Jeff Th M. ; ten Brinke, Gerrit ; Loos, Katja. / Supramolecular Route to Well-Ordered Metal Nanofoams. In: Acs Nano. 2011 ; Vol. 5, No. 8. pp. 6339-6348.

Harvard

Vukovic, I, Punzhin, S, Vukovic, Z, Onck, P, De Hosson, JTM, ten Brinke, G & Loos, K 2011, 'Supramolecular Route to Well-Ordered Metal Nanofoams', Acs Nano, vol. 5, no. 8, pp. 6339-6348. https://doi.org/10.1021/nn201421y

Standard

Supramolecular Route to Well-Ordered Metal Nanofoams. / Vukovic, Ivana; Punzhin, Sergey; Vukovic, Zorica; Onck, Patrick; De Hosson, Jeff Th M.; ten Brinke, Gerrit; Loos, Katja.

In: Acs Nano, Vol. 5, No. 8, 08.2011, p. 6339-6348.

Research output: Contribution to journalArticleAcademicpeer-review

Vancouver

Vukovic I, Punzhin S, Vukovic Z, Onck P, De Hosson JTM, ten Brinke G et al. Supramolecular Route to Well-Ordered Metal Nanofoams. Acs Nano. 2011 Aug;5(8):6339-6348. https://doi.org/10.1021/nn201421y


BibTeX

@article{e80bfb3ebd5943f48641065fdd99da66,
title = "Supramolecular Route to Well-Ordered Metal Nanofoams",
abstract = "Metal nanofoams with a porosity above 50% v/v have recently attracted great. Interest In materials science due to their interesting properties.. We.. demonstrate a new straightforward route to prepare such nanofoams using diblock copolymer-based PS-block-P4VP-(PDP) supramolecules that self-assemble Into a bicontinuous gyroid morphology, consisting of PS network channels in a P4VP(PDP) matrix. After dissolving the PDP, the P4VP. collapses onto the PS struts and a free-standing bicontinuous. gyroid template of 50-100 mu m thickness and interconnected, uniformly sized pores Is formed. The hydrophilic P4VP corona facilitates the penetration of water-based plating reagents into the porous template and enables a successful metal deposition. After plating, the polymer is simply degraded by heating, resulting In a well-ordered inverse gyroid nickel-foam. Essential to this approach Is the removal of only one part of the matrix (i.e., PDP). Therefore, the template accounts for 50% v/v or more. The porosity characteristics (amount, size of pores) can be tuned by selecting the appropriate copolymer and by adjusting the amount of PDP.",
keywords = "metal nanofoams, nanopores, diblock copolymers, supramolecules, metal plating, BLOCK-COPOLYMERS, THIN-FILMS, DIBLOCK COPOLYMERS, STRONG SEGREGATION, SURFACE-STRESS, POLYSTYRENE, MORPHOLOGY, TEMPLATES, PHASE, NANOCHANNELS",
author = "Ivana Vukovic and Sergey Punzhin and Zorica Vukovic and Patrick Onck and {De Hosson}, {Jeff Th M.} and {ten Brinke}, Gerrit and Katja Loos",
year = "2011",
month = aug,
doi = "10.1021/nn201421y",
language = "English",
volume = "5",
pages = "6339--6348",
journal = "Acs Nano",
issn = "1936-0851",
publisher = "AMER CHEMICAL SOC",
number = "8",

}

RIS

TY - JOUR

T1 - Supramolecular Route to Well-Ordered Metal Nanofoams

AU - Vukovic, Ivana

AU - Punzhin, Sergey

AU - Vukovic, Zorica

AU - Onck, Patrick

AU - De Hosson, Jeff Th M.

AU - ten Brinke, Gerrit

AU - Loos, Katja

PY - 2011/8

Y1 - 2011/8

N2 - Metal nanofoams with a porosity above 50% v/v have recently attracted great. Interest In materials science due to their interesting properties.. We.. demonstrate a new straightforward route to prepare such nanofoams using diblock copolymer-based PS-block-P4VP-(PDP) supramolecules that self-assemble Into a bicontinuous gyroid morphology, consisting of PS network channels in a P4VP(PDP) matrix. After dissolving the PDP, the P4VP. collapses onto the PS struts and a free-standing bicontinuous. gyroid template of 50-100 mu m thickness and interconnected, uniformly sized pores Is formed. The hydrophilic P4VP corona facilitates the penetration of water-based plating reagents into the porous template and enables a successful metal deposition. After plating, the polymer is simply degraded by heating, resulting In a well-ordered inverse gyroid nickel-foam. Essential to this approach Is the removal of only one part of the matrix (i.e., PDP). Therefore, the template accounts for 50% v/v or more. The porosity characteristics (amount, size of pores) can be tuned by selecting the appropriate copolymer and by adjusting the amount of PDP.

AB - Metal nanofoams with a porosity above 50% v/v have recently attracted great. Interest In materials science due to their interesting properties.. We.. demonstrate a new straightforward route to prepare such nanofoams using diblock copolymer-based PS-block-P4VP-(PDP) supramolecules that self-assemble Into a bicontinuous gyroid morphology, consisting of PS network channels in a P4VP(PDP) matrix. After dissolving the PDP, the P4VP. collapses onto the PS struts and a free-standing bicontinuous. gyroid template of 50-100 mu m thickness and interconnected, uniformly sized pores Is formed. The hydrophilic P4VP corona facilitates the penetration of water-based plating reagents into the porous template and enables a successful metal deposition. After plating, the polymer is simply degraded by heating, resulting In a well-ordered inverse gyroid nickel-foam. Essential to this approach Is the removal of only one part of the matrix (i.e., PDP). Therefore, the template accounts for 50% v/v or more. The porosity characteristics (amount, size of pores) can be tuned by selecting the appropriate copolymer and by adjusting the amount of PDP.

KW - metal nanofoams

KW - nanopores

KW - diblock copolymers

KW - supramolecules

KW - metal plating

KW - BLOCK-COPOLYMERS

KW - THIN-FILMS

KW - DIBLOCK COPOLYMERS

KW - STRONG SEGREGATION

KW - SURFACE-STRESS

KW - POLYSTYRENE

KW - MORPHOLOGY

KW - TEMPLATES

KW - PHASE

KW - NANOCHANNELS

U2 - 10.1021/nn201421y

DO - 10.1021/nn201421y

M3 - Article

VL - 5

SP - 6339

EP - 6348

JO - Acs Nano

JF - Acs Nano

SN - 1936-0851

IS - 8

ER -

ID: 5388193