Publication

Stable Polymer Micelles Formed by Metal Coordination

Wang, J., Stuart, M. A. C., Marcelis, A. T. M., Colomb-Delsuc, M., Otto, S. & van der Gucht, J., 11-Sep-2012, In : Macromolecules. 45, 17, p. 7179-7185 7 p.

Research output: Contribution to journalArticleAcademicpeer-review

APA

Wang, J., Stuart, M. A. C., Marcelis, A. T. M., Colomb-Delsuc, M., Otto, S., & van der Gucht, J. (2012). Stable Polymer Micelles Formed by Metal Coordination. Macromolecules, 45(17), 7179-7185. https://doi.org/10.1021/ma301323z

Author

Wang, Junyou ; Stuart, Martien A. Cohen ; Marcelis, Antonius T. M. ; Colomb-Delsuc, Mathieu ; Otto, Sijbren ; van der Gucht, Jasper. / Stable Polymer Micelles Formed by Metal Coordination. In: Macromolecules. 2012 ; Vol. 45, No. 17. pp. 7179-7185.

Harvard

Wang, J, Stuart, MAC, Marcelis, ATM, Colomb-Delsuc, M, Otto, S & van der Gucht, J 2012, 'Stable Polymer Micelles Formed by Metal Coordination', Macromolecules, vol. 45, no. 17, pp. 7179-7185. https://doi.org/10.1021/ma301323z

Standard

Stable Polymer Micelles Formed by Metal Coordination. / Wang, Junyou; Stuart, Martien A. Cohen; Marcelis, Antonius T. M.; Colomb-Delsuc, Mathieu; Otto, Sijbren; van der Gucht, Jasper.

In: Macromolecules, Vol. 45, No. 17, 11.09.2012, p. 7179-7185.

Research output: Contribution to journalArticleAcademicpeer-review

Vancouver

Wang J, Stuart MAC, Marcelis ATM, Colomb-Delsuc M, Otto S, van der Gucht J. Stable Polymer Micelles Formed by Metal Coordination. Macromolecules. 2012 Sep 11;45(17):7179-7185. https://doi.org/10.1021/ma301323z


BibTeX

@article{0e6f7b0bb8bc4181915821453713ec52,
title = "Stable Polymer Micelles Formed by Metal Coordination",
abstract = "Metal-containing polymer micelles have attracted much attention due to their potential for medical and nanotechnological applications. In this paper, we present a method to prepare stable metal-containing polymer micelles. A diblock copolymer poly(4-vinylpyridine)-b-poly(ethylene oxide) (P4VP(48)-b-PEO193) with terdendate ligand groups grafted to the PVP block is synthesized. Added metal ions cross-link the ligand-carrying blocks together, while the hydrophilic block stabilizes the formed coordination complex, leading to the formation of micelles. The structure and stability of the formed micelles are investigated by light scattering and cyro-TEM. The strong coordination bonds provide high stability of the micelles: adding salt or EDTA hardly affects the formed micelles.",
keywords = "COACERVATE CORE MICELLES, BLOCK-COPOLYMER MICELLES, INTEGRAL-EQUATIONS, COMPLEX, NANOPARTICLES, STABILITY, DIBLOCK, BINDING, LIGAND, IONS",
author = "Junyou Wang and Stuart, {Martien A. Cohen} and Marcelis, {Antonius T. M.} and Mathieu Colomb-Delsuc and Sijbren Otto and {van der Gucht}, Jasper",
note = "PT: J; TC: 0; UT: WOS:000309014000046",
year = "2012",
month = "9",
day = "11",
doi = "10.1021/ma301323z",
language = "English",
volume = "45",
pages = "7179--7185",
journal = "Macromolecules",
issn = "0024-9297",
publisher = "AMER CHEMICAL SOC",
number = "17",

}

RIS

TY - JOUR

T1 - Stable Polymer Micelles Formed by Metal Coordination

AU - Wang, Junyou

AU - Stuart, Martien A. Cohen

AU - Marcelis, Antonius T. M.

AU - Colomb-Delsuc, Mathieu

AU - Otto, Sijbren

AU - van der Gucht, Jasper

N1 - PT: J; TC: 0; UT: WOS:000309014000046

PY - 2012/9/11

Y1 - 2012/9/11

N2 - Metal-containing polymer micelles have attracted much attention due to their potential for medical and nanotechnological applications. In this paper, we present a method to prepare stable metal-containing polymer micelles. A diblock copolymer poly(4-vinylpyridine)-b-poly(ethylene oxide) (P4VP(48)-b-PEO193) with terdendate ligand groups grafted to the PVP block is synthesized. Added metal ions cross-link the ligand-carrying blocks together, while the hydrophilic block stabilizes the formed coordination complex, leading to the formation of micelles. The structure and stability of the formed micelles are investigated by light scattering and cyro-TEM. The strong coordination bonds provide high stability of the micelles: adding salt or EDTA hardly affects the formed micelles.

AB - Metal-containing polymer micelles have attracted much attention due to their potential for medical and nanotechnological applications. In this paper, we present a method to prepare stable metal-containing polymer micelles. A diblock copolymer poly(4-vinylpyridine)-b-poly(ethylene oxide) (P4VP(48)-b-PEO193) with terdendate ligand groups grafted to the PVP block is synthesized. Added metal ions cross-link the ligand-carrying blocks together, while the hydrophilic block stabilizes the formed coordination complex, leading to the formation of micelles. The structure and stability of the formed micelles are investigated by light scattering and cyro-TEM. The strong coordination bonds provide high stability of the micelles: adding salt or EDTA hardly affects the formed micelles.

KW - COACERVATE CORE MICELLES

KW - BLOCK-COPOLYMER MICELLES

KW - INTEGRAL-EQUATIONS

KW - COMPLEX

KW - NANOPARTICLES

KW - STABILITY

KW - DIBLOCK

KW - BINDING

KW - LIGAND

KW - IONS

U2 - 10.1021/ma301323z

DO - 10.1021/ma301323z

M3 - Article

VL - 45

SP - 7179

EP - 7185

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 17

ER -

ID: 2308745