Publication

Self-Organization in Solutions of Stiff-Chain Amphiphilic Macromolecules

Vasilevskaya, V. V., Markov, V. A., ten Brinke, G. & Khokhlov, A. R., 28-Oct-2008, In : Macromolecules. 41, 20, p. 7722-7728 7 p.

Research output: Contribution to journalArticleAcademicpeer-review

APA

Vasilevskaya, V. V., Markov, V. A., ten Brinke, G., & Khokhlov, A. R. (2008). Self-Organization in Solutions of Stiff-Chain Amphiphilic Macromolecules. Macromolecules, 41(20), 7722-7728. https://doi.org/10.1021/ma800465j

Author

Vasilevskaya, V. V. ; Markov, V. A. ; ten Brinke, G. ; Khokhlov, A. R. / Self-Organization in Solutions of Stiff-Chain Amphiphilic Macromolecules. In: Macromolecules. 2008 ; Vol. 41, No. 20. pp. 7722-7728.

Harvard

Vasilevskaya, VV, Markov, VA, ten Brinke, G & Khokhlov, AR 2008, 'Self-Organization in Solutions of Stiff-Chain Amphiphilic Macromolecules', Macromolecules, vol. 41, no. 20, pp. 7722-7728. https://doi.org/10.1021/ma800465j

Standard

Self-Organization in Solutions of Stiff-Chain Amphiphilic Macromolecules. / Vasilevskaya, V. V.; Markov, V. A.; ten Brinke, G.; Khokhlov, A. R.

In: Macromolecules, Vol. 41, No. 20, 28.10.2008, p. 7722-7728.

Research output: Contribution to journalArticleAcademicpeer-review

Vancouver

Vasilevskaya VV, Markov VA, ten Brinke G, Khokhlov AR. Self-Organization in Solutions of Stiff-Chain Amphiphilic Macromolecules. Macromolecules. 2008 Oct 28;41(20):7722-7728. https://doi.org/10.1021/ma800465j


BibTeX

@article{f3800e9dd8924db0b51dc00e0c681cf2,
title = "Self-Organization in Solutions of Stiff-Chain Amphiphilic Macromolecules",
abstract = "Conformational properties of amphiphilic stiff-chain macromolecules in concentrated solutions in poor solvent have been Studied via computer modeling. We have found that the conformational state of macromolecules ill such systems depends oil the macromolecular Stiffness and oil the way the Solution hits been prepared. Thus, if the concentration of globules increased from a very diluted Solution. the globules remain stable, independent of the macromolecular stiffness, and do not aggregate even in concentrated Solutions. Oil the other hand, if the solvent quality is gradually decreased in I solution with a concentration much larger than that of a semidilute solution, then relatively flexible chains form separate globules. whereas semirigid macromolecules tend to aggregate and form braid-like conformations. The results obtained agree with the published experimental data and call he used for directed synthesis of macromolecules modelin, the behavior of biopolymers.",
keywords = "MONTE-CARLO-SIMULATION, COIL-GLOBULE TRANSITION, 2-DIMENSIONAL CLASSIFICATION, PARTITIONING PROPERTIES, AQUEOUS-SOLUTIONS, LENGTH, DIAGRAM, POLYELECTROLYTES, CONFORMATION, EQUILIBRIUM",
author = "Vasilevskaya, {V. V.} and Markov, {V. A.} and {ten Brinke}, G. and Khokhlov, {A. R.}",
year = "2008",
month = "10",
day = "28",
doi = "10.1021/ma800465j",
language = "English",
volume = "41",
pages = "7722--7728",
journal = "Macromolecules",
issn = "0024-9297",
publisher = "AMER CHEMICAL SOC",
number = "20",

}

RIS

TY - JOUR

T1 - Self-Organization in Solutions of Stiff-Chain Amphiphilic Macromolecules

AU - Vasilevskaya, V. V.

AU - Markov, V. A.

AU - ten Brinke, G.

AU - Khokhlov, A. R.

PY - 2008/10/28

Y1 - 2008/10/28

N2 - Conformational properties of amphiphilic stiff-chain macromolecules in concentrated solutions in poor solvent have been Studied via computer modeling. We have found that the conformational state of macromolecules ill such systems depends oil the macromolecular Stiffness and oil the way the Solution hits been prepared. Thus, if the concentration of globules increased from a very diluted Solution. the globules remain stable, independent of the macromolecular stiffness, and do not aggregate even in concentrated Solutions. Oil the other hand, if the solvent quality is gradually decreased in I solution with a concentration much larger than that of a semidilute solution, then relatively flexible chains form separate globules. whereas semirigid macromolecules tend to aggregate and form braid-like conformations. The results obtained agree with the published experimental data and call he used for directed synthesis of macromolecules modelin, the behavior of biopolymers.

AB - Conformational properties of amphiphilic stiff-chain macromolecules in concentrated solutions in poor solvent have been Studied via computer modeling. We have found that the conformational state of macromolecules ill such systems depends oil the macromolecular Stiffness and oil the way the Solution hits been prepared. Thus, if the concentration of globules increased from a very diluted Solution. the globules remain stable, independent of the macromolecular stiffness, and do not aggregate even in concentrated Solutions. Oil the other hand, if the solvent quality is gradually decreased in I solution with a concentration much larger than that of a semidilute solution, then relatively flexible chains form separate globules. whereas semirigid macromolecules tend to aggregate and form braid-like conformations. The results obtained agree with the published experimental data and call he used for directed synthesis of macromolecules modelin, the behavior of biopolymers.

KW - MONTE-CARLO-SIMULATION

KW - COIL-GLOBULE TRANSITION

KW - 2-DIMENSIONAL CLASSIFICATION

KW - PARTITIONING PROPERTIES

KW - AQUEOUS-SOLUTIONS

KW - LENGTH

KW - DIAGRAM

KW - POLYELECTROLYTES

KW - CONFORMATION

KW - EQUILIBRIUM

U2 - 10.1021/ma800465j

DO - 10.1021/ma800465j

M3 - Article

VL - 41

SP - 7722

EP - 7728

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 20

ER -

ID: 4793124