Publication

Poly(4-vinylpyridine)-block-poly(N-acryloylpiperidine) diblock copolymers: synthesis, self-assembly and interaction

Hofman, A. H., Alberda van Ekenstein, G., Woortman, A., ten Brinke, G. & Loos, K., 1-Oct-2015, In : Polymer Chemistry. 6, 39, p. 7015-7026 12 p.

Research output: Contribution to journalArticleAcademicpeer-review

APA

Hofman, A. H., Alberda van Ekenstein, G., Woortman, A., ten Brinke, G., & Loos, K. (2015). Poly(4-vinylpyridine)-block-poly(N-acryloylpiperidine) diblock copolymers: synthesis, self-assembly and interaction. Polymer Chemistry, 6(39), 7015-7026. https://doi.org/10.1039/C5PY00952A

Author

Hofman, Anton H. ; Alberda van Ekenstein, Gerhard ; Woortman, Albert ; ten Brinke, Gerrit ; Loos, Katja. / Poly(4-vinylpyridine)-block-poly(N-acryloylpiperidine) diblock copolymers: synthesis, self-assembly and interaction. In: Polymer Chemistry. 2015 ; Vol. 6, No. 39. pp. 7015-7026.

Harvard

Hofman, AH, Alberda van Ekenstein, G, Woortman, A, ten Brinke, G & Loos, K 2015, 'Poly(4-vinylpyridine)-block-poly(N-acryloylpiperidine) diblock copolymers: synthesis, self-assembly and interaction', Polymer Chemistry, vol. 6, no. 39, pp. 7015-7026. https://doi.org/10.1039/C5PY00952A

Standard

Poly(4-vinylpyridine)-block-poly(N-acryloylpiperidine) diblock copolymers: synthesis, self-assembly and interaction. / Hofman, Anton H.; Alberda van Ekenstein, Gerhard; Woortman, Albert; ten Brinke, Gerrit; Loos, Katja.

In: Polymer Chemistry, Vol. 6, No. 39, 01.10.2015, p. 7015-7026.

Research output: Contribution to journalArticleAcademicpeer-review

Vancouver

Hofman AH, Alberda van Ekenstein G, Woortman A, ten Brinke G, Loos K. Poly(4-vinylpyridine)-block-poly(N-acryloylpiperidine) diblock copolymers: synthesis, self-assembly and interaction. Polymer Chemistry. 2015 Oct 1;6(39):7015-7026. https://doi.org/10.1039/C5PY00952A


BibTeX

@article{55e0732b73ee46c0b1336d8d65cb6c47,
title = "Poly(4-vinylpyridine)-block-poly(N-acryloylpiperidine) diblock copolymers: synthesis, self-assembly and interaction",
abstract = "Controlled radical polymerization of 4-vinylpyridine (4VP) and N-acryloylpiperidine (API) by the RAFT process allowed preparation of well-defined double hydrogen bond accepting P4VP-b-PAPI diblock copolymers. The miscibility of this new monomer pair was studied via a random copolymer blend approach and resulted in a Flory–Huggins interaction parameter χ4VP,API ≈ 0.03, which is higher than the commonly used styrene/MMA couple, but lower compared to styrene/isoprene. This value was found to support the bulk phase behavior of a series of diblock copolymers as evidenced by SAXS and TEM. Highly ordered structures, including cylinders, lamellae and spheres, were identified in these materials, even in diblocks of higher molecular weight and broader distribution, while a disordered morphology was indeed observed in a symmetric, low molecular weight analogue.",
author = "Hofman, {Anton H.} and {Alberda van Ekenstein}, Gerhard and Albert Woortman and {ten Brinke}, Gerrit and Katja Loos",
year = "2015",
month = "10",
day = "1",
doi = "10.1039/C5PY00952A",
language = "English",
volume = "6",
pages = "7015--7026",
journal = "Polymer Chemistry",
issn = "1759-9954",
publisher = "ROYAL SOC CHEMISTRY",
number = "39",

}

RIS

TY - JOUR

T1 - Poly(4-vinylpyridine)-block-poly(N-acryloylpiperidine) diblock copolymers: synthesis, self-assembly and interaction

AU - Hofman, Anton H.

AU - Alberda van Ekenstein, Gerhard

AU - Woortman, Albert

AU - ten Brinke, Gerrit

AU - Loos, Katja

PY - 2015/10/1

Y1 - 2015/10/1

N2 - Controlled radical polymerization of 4-vinylpyridine (4VP) and N-acryloylpiperidine (API) by the RAFT process allowed preparation of well-defined double hydrogen bond accepting P4VP-b-PAPI diblock copolymers. The miscibility of this new monomer pair was studied via a random copolymer blend approach and resulted in a Flory–Huggins interaction parameter χ4VP,API ≈ 0.03, which is higher than the commonly used styrene/MMA couple, but lower compared to styrene/isoprene. This value was found to support the bulk phase behavior of a series of diblock copolymers as evidenced by SAXS and TEM. Highly ordered structures, including cylinders, lamellae and spheres, were identified in these materials, even in diblocks of higher molecular weight and broader distribution, while a disordered morphology was indeed observed in a symmetric, low molecular weight analogue.

AB - Controlled radical polymerization of 4-vinylpyridine (4VP) and N-acryloylpiperidine (API) by the RAFT process allowed preparation of well-defined double hydrogen bond accepting P4VP-b-PAPI diblock copolymers. The miscibility of this new monomer pair was studied via a random copolymer blend approach and resulted in a Flory–Huggins interaction parameter χ4VP,API ≈ 0.03, which is higher than the commonly used styrene/MMA couple, but lower compared to styrene/isoprene. This value was found to support the bulk phase behavior of a series of diblock copolymers as evidenced by SAXS and TEM. Highly ordered structures, including cylinders, lamellae and spheres, were identified in these materials, even in diblocks of higher molecular weight and broader distribution, while a disordered morphology was indeed observed in a symmetric, low molecular weight analogue.

U2 - 10.1039/C5PY00952A

DO - 10.1039/C5PY00952A

M3 - Article

VL - 6

SP - 7015

EP - 7026

JO - Polymer Chemistry

JF - Polymer Chemistry

SN - 1759-9954

IS - 39

ER -

ID: 24037800