Publication

Order-disorder transition in supramolecular polymer combs/brushes with polymeric side chains

Golkaram, M., Portale, G., Mulder, P., Maniar, D., Faraji, S. & Loos, K., 21-Apr-2020, In : Polymer Chemistry. 11, 15, p. 2749-2760 12 p.

Research output: Contribution to journalArticleAcademicpeer-review

APA

Golkaram, M., Portale, G., Mulder, P., Maniar, D., Faraji, S., & Loos, K. (2020). Order-disorder transition in supramolecular polymer combs/brushes with polymeric side chains. Polymer Chemistry, 11(15), 2749-2760. https://doi.org/10.1039/c9py01915d

Author

Golkaram, Milad ; Portale, Giuseppe ; Mulder, Pascal ; Maniar, Dina ; Faraji, Shirin ; Loos, Katja. / Order-disorder transition in supramolecular polymer combs/brushes with polymeric side chains. In: Polymer Chemistry. 2020 ; Vol. 11, No. 15. pp. 2749-2760.

Harvard

Golkaram, M, Portale, G, Mulder, P, Maniar, D, Faraji, S & Loos, K 2020, 'Order-disorder transition in supramolecular polymer combs/brushes with polymeric side chains', Polymer Chemistry, vol. 11, no. 15, pp. 2749-2760. https://doi.org/10.1039/c9py01915d

Standard

Order-disorder transition in supramolecular polymer combs/brushes with polymeric side chains. / Golkaram, Milad; Portale, Giuseppe; Mulder, Pascal; Maniar, Dina; Faraji, Shirin; Loos, Katja.

In: Polymer Chemistry, Vol. 11, No. 15, 21.04.2020, p. 2749-2760.

Research output: Contribution to journalArticleAcademicpeer-review

Vancouver

Golkaram M, Portale G, Mulder P, Maniar D, Faraji S, Loos K. Order-disorder transition in supramolecular polymer combs/brushes with polymeric side chains. Polymer Chemistry. 2020 Apr 21;11(15):2749-2760. https://doi.org/10.1039/c9py01915d


BibTeX

@article{7279410782164693a087335441c71e5b,
title = "Order-disorder transition in supramolecular polymer combs/brushes with polymeric side chains",
abstract = "Supramolecular polymer combs/brushes can be used as smart materials which incorporate the properties of linear polymers with branch polymers depending on the temperature, grafting density, branch molecular weight and most importantly type of non-covalent interaction between the main chain and side chains. Three sets of polymers were synthesized and mixed based on a specific interaction between the main chain and the side chain polymers. The first two sets based on the combination of 2,4-diamino-1,3,5-triazine (DAT) : thymine (THY) and 2-ureido-4[1H]-pyrimidinone (UPy) : (1-(6-isocyanatohexyl)-3-(7-oxo-7,8-dihydro-1,8-naphthyridin-2-yl)urea) (ODIN) were a blend and the third one using ODIN : ODIN interactions was used without a main chain. The polymer set using ODIN : ODIN interaction showed long-range ordering due to strong ODIN aggregation, whereas UPy : ODIN-based polymer combs showed comb-like clusters without any ordering. The phase separation in the THY : DAT system was more pronounced and was further improved after the addition of more equivalents of side chains. Moreover, using melt rheology, consistent with the SAXS data, it was concluded that long-range ordering is responsible for the elastic properties and the flow temperature (T-flow) is lower than the order-disorder transition temperature (T-ODT). This work can be considered as a toolkit for the design of bottlebrush and comb polymers as well as supersoft elastomers and stimuli-responsive materials.",
keywords = "MECHANICAL-PROPERTIES, GRAFT-COPOLYMERS, UREIDO-CYTOSINE, COMB POLYMERS, DYNAMICS, RHEOLOGY, MELT, ORGANIZATION, AGGREGATION, SEGREGATION",
author = "Milad Golkaram and Giuseppe Portale and Pascal Mulder and Dina Maniar and Shirin Faraji and Katja Loos",
year = "2020",
month = "4",
day = "21",
doi = "10.1039/c9py01915d",
language = "English",
volume = "11",
pages = "2749--2760",
journal = "Polymer Chemistry",
issn = "1759-9954",
publisher = "ROYAL SOC CHEMISTRY",
number = "15",

}

RIS

TY - JOUR

T1 - Order-disorder transition in supramolecular polymer combs/brushes with polymeric side chains

AU - Golkaram, Milad

AU - Portale, Giuseppe

AU - Mulder, Pascal

AU - Maniar, Dina

AU - Faraji, Shirin

AU - Loos, Katja

PY - 2020/4/21

Y1 - 2020/4/21

N2 - Supramolecular polymer combs/brushes can be used as smart materials which incorporate the properties of linear polymers with branch polymers depending on the temperature, grafting density, branch molecular weight and most importantly type of non-covalent interaction between the main chain and side chains. Three sets of polymers were synthesized and mixed based on a specific interaction between the main chain and the side chain polymers. The first two sets based on the combination of 2,4-diamino-1,3,5-triazine (DAT) : thymine (THY) and 2-ureido-4[1H]-pyrimidinone (UPy) : (1-(6-isocyanatohexyl)-3-(7-oxo-7,8-dihydro-1,8-naphthyridin-2-yl)urea) (ODIN) were a blend and the third one using ODIN : ODIN interactions was used without a main chain. The polymer set using ODIN : ODIN interaction showed long-range ordering due to strong ODIN aggregation, whereas UPy : ODIN-based polymer combs showed comb-like clusters without any ordering. The phase separation in the THY : DAT system was more pronounced and was further improved after the addition of more equivalents of side chains. Moreover, using melt rheology, consistent with the SAXS data, it was concluded that long-range ordering is responsible for the elastic properties and the flow temperature (T-flow) is lower than the order-disorder transition temperature (T-ODT). This work can be considered as a toolkit for the design of bottlebrush and comb polymers as well as supersoft elastomers and stimuli-responsive materials.

AB - Supramolecular polymer combs/brushes can be used as smart materials which incorporate the properties of linear polymers with branch polymers depending on the temperature, grafting density, branch molecular weight and most importantly type of non-covalent interaction between the main chain and side chains. Three sets of polymers were synthesized and mixed based on a specific interaction between the main chain and the side chain polymers. The first two sets based on the combination of 2,4-diamino-1,3,5-triazine (DAT) : thymine (THY) and 2-ureido-4[1H]-pyrimidinone (UPy) : (1-(6-isocyanatohexyl)-3-(7-oxo-7,8-dihydro-1,8-naphthyridin-2-yl)urea) (ODIN) were a blend and the third one using ODIN : ODIN interactions was used without a main chain. The polymer set using ODIN : ODIN interaction showed long-range ordering due to strong ODIN aggregation, whereas UPy : ODIN-based polymer combs showed comb-like clusters without any ordering. The phase separation in the THY : DAT system was more pronounced and was further improved after the addition of more equivalents of side chains. Moreover, using melt rheology, consistent with the SAXS data, it was concluded that long-range ordering is responsible for the elastic properties and the flow temperature (T-flow) is lower than the order-disorder transition temperature (T-ODT). This work can be considered as a toolkit for the design of bottlebrush and comb polymers as well as supersoft elastomers and stimuli-responsive materials.

KW - MECHANICAL-PROPERTIES

KW - GRAFT-COPOLYMERS

KW - UREIDO-CYTOSINE

KW - COMB POLYMERS

KW - DYNAMICS

KW - RHEOLOGY

KW - MELT

KW - ORGANIZATION

KW - AGGREGATION

KW - SEGREGATION

U2 - 10.1039/c9py01915d

DO - 10.1039/c9py01915d

M3 - Article

VL - 11

SP - 2749

EP - 2760

JO - Polymer Chemistry

JF - Polymer Chemistry

SN - 1759-9954

IS - 15

ER -

ID: 125137561