Publication

Hydrogen peroxide modified Mg-Al-O oxides supported Pt-Sn catalysts for paraffin dehydrogenation

Lai, Y., He, S., Luo, S., Bi, W., Li, X., Sun, C. & Seshan, K., 5-Sep-2015, In : Catalysis Communications. 69, p. 39-42 4 p.

Research output: Contribution to journalArticleAcademicpeer-review

  • Yulong Lai
  • Songbo He
  • Sha Luo
  • Wenjun Bi
  • Xianru Li
  • Chenglin Sun
  • K. Seshan

In this work, a new method to prepare Mg-Al-O oxide by co-precipitation method with addition of H2O2 was developed. The application of Mg-Al-O as a support of Pt-Sn catalysts for paraffin dehydrogenation was investigated. Characterization results indicated that modification of H2O2 (i) enlarged the pore structure and decreased the density and mechanical strength of the Mg-Al-O oxide and (ii) increased the platinum dispersion, weakened the acidity of the Pt-Sn/Mg-Al-O catalysts. Dehydrogenation of n-dodecane results showed that modification of H2O2 (iii) improved the paraffin conversion and olefin selectivity; (iv) inhibited the coke deposition on the catalyst and (v) extended the catalyst life-time. (C) 2015 Elsevier B.V. All rights reserved.

Original languageEnglish
Pages (from-to)39-42
Number of pages4
JournalCatalysis Communications
Volume69
Publication statusPublished - 5-Sep-2015
Externally publishedYes

    Keywords

  • H2O2, Mg-Al, Pt-Sn catalysts, Dehydrogenation, Paraffin, SELECTIVITY, SIMULATION, OLEFIN, SILICA, SIZE

ID: 55600878