Publication

High-Yield 5-Hydroxymethylfurfural Synthesis from Crude Sugar Beet Juice in a Biphasic Microreactor

Abdilla-Santes, R. M., Guo, W., Bruijnincx, P. C. A., Yue, J., Deuss, P. J. & Heeres, H. J., 20-Sep-2019, In : Chemsuschem. 12, 18, p. 4304-4312 9 p.

Research output: Contribution to journalArticleAcademicpeer-review

APA

Abdilla-Santes, R. M., Guo, W., Bruijnincx, P. C. A., Yue, J., Deuss, P. J., & Heeres, H. J. (2019). High-Yield 5-Hydroxymethylfurfural Synthesis from Crude Sugar Beet Juice in a Biphasic Microreactor. Chemsuschem, 12(18), 4304-4312. https://doi.org/10.1002/cssc.201901115

Author

Abdilla-Santes, Ria M. ; Guo, Wenze ; Bruijnincx, Pieter C. A. ; Yue, Jun ; Deuss, Peter J. ; Heeres, Hero J. / High-Yield 5-Hydroxymethylfurfural Synthesis from Crude Sugar Beet Juice in a Biphasic Microreactor. In: Chemsuschem. 2019 ; Vol. 12, No. 18. pp. 4304-4312.

Harvard

Abdilla-Santes, RM, Guo, W, Bruijnincx, PCA, Yue, J, Deuss, PJ & Heeres, HJ 2019, 'High-Yield 5-Hydroxymethylfurfural Synthesis from Crude Sugar Beet Juice in a Biphasic Microreactor', Chemsuschem, vol. 12, no. 18, pp. 4304-4312. https://doi.org/10.1002/cssc.201901115

Standard

High-Yield 5-Hydroxymethylfurfural Synthesis from Crude Sugar Beet Juice in a Biphasic Microreactor. / Abdilla-Santes, Ria M.; Guo, Wenze; Bruijnincx, Pieter C. A.; Yue, Jun; Deuss, Peter J.; Heeres, Hero J.

In: Chemsuschem, Vol. 12, No. 18, 20.09.2019, p. 4304-4312.

Research output: Contribution to journalArticleAcademicpeer-review

Vancouver

Abdilla-Santes RM, Guo W, Bruijnincx PCA, Yue J, Deuss PJ, Heeres HJ. High-Yield 5-Hydroxymethylfurfural Synthesis from Crude Sugar Beet Juice in a Biphasic Microreactor. Chemsuschem. 2019 Sep 20;12(18):4304-4312. https://doi.org/10.1002/cssc.201901115


BibTeX

@article{bbc8856a6bae46768e6d290478edeb2e,
title = "High-Yield 5-Hydroxymethylfurfural Synthesis from Crude Sugar Beet Juice in a Biphasic Microreactor",
abstract = "5-Hydroxymethylfurfural (HMF) is an important biobased platform chemical obtainable in high selectivity by the hydrolysis of fructose (FRC). However, FRC is expensive, making the production of HMF at a competitive market price highly challenging. Here, it is shown that sugar beet thick juice, a crude, sucrose-rich intermediate in sugar refining, is an excellent feedstock for HMF synthesis. Unprecedented high selectivities and yields of >90 % for HMF were achieved in a biphasic reactor setup at 150 degrees C using salted diluted thick juice with H2SO4 as catalyst and 2-methyltetrahydrofuran as a bioderived extraction solvent. The conversion of glucose, obtained by sucrose inversion, could be limited to",
keywords = "5-hydroxymethylfurfural, biobased chemicals, microreactors, renewable resources, sucrose, EFFICIENT PRODUCTION, HYDROGEN-TRANSFER, THICK JUICE, CONVERSION, DEHYDRATION, GLUCOSE, BIOMASS, ACID, FRUCTOSE, PLATFORM",
author = "Abdilla-Santes, {Ria M.} and Wenze Guo and Bruijnincx, {Pieter C. A.} and Jun Yue and Deuss, {Peter J.} and Heeres, {Hero J.}",
year = "2019",
month = sep,
day = "20",
doi = "10.1002/cssc.201901115",
language = "English",
volume = "12",
pages = "4304--4312",
journal = "Chemsuschem",
issn = "1864-5631",
publisher = "WILEY-V C H VERLAG GMBH",
number = "18",

}

RIS

TY - JOUR

T1 - High-Yield 5-Hydroxymethylfurfural Synthesis from Crude Sugar Beet Juice in a Biphasic Microreactor

AU - Abdilla-Santes, Ria M.

AU - Guo, Wenze

AU - Bruijnincx, Pieter C. A.

AU - Yue, Jun

AU - Deuss, Peter J.

AU - Heeres, Hero J.

PY - 2019/9/20

Y1 - 2019/9/20

N2 - 5-Hydroxymethylfurfural (HMF) is an important biobased platform chemical obtainable in high selectivity by the hydrolysis of fructose (FRC). However, FRC is expensive, making the production of HMF at a competitive market price highly challenging. Here, it is shown that sugar beet thick juice, a crude, sucrose-rich intermediate in sugar refining, is an excellent feedstock for HMF synthesis. Unprecedented high selectivities and yields of >90 % for HMF were achieved in a biphasic reactor setup at 150 degrees C using salted diluted thick juice with H2SO4 as catalyst and 2-methyltetrahydrofuran as a bioderived extraction solvent. The conversion of glucose, obtained by sucrose inversion, could be limited to

AB - 5-Hydroxymethylfurfural (HMF) is an important biobased platform chemical obtainable in high selectivity by the hydrolysis of fructose (FRC). However, FRC is expensive, making the production of HMF at a competitive market price highly challenging. Here, it is shown that sugar beet thick juice, a crude, sucrose-rich intermediate in sugar refining, is an excellent feedstock for HMF synthesis. Unprecedented high selectivities and yields of >90 % for HMF were achieved in a biphasic reactor setup at 150 degrees C using salted diluted thick juice with H2SO4 as catalyst and 2-methyltetrahydrofuran as a bioderived extraction solvent. The conversion of glucose, obtained by sucrose inversion, could be limited to

KW - 5-hydroxymethylfurfural

KW - biobased chemicals

KW - microreactors

KW - renewable resources

KW - sucrose

KW - EFFICIENT PRODUCTION

KW - HYDROGEN-TRANSFER

KW - THICK JUICE

KW - CONVERSION

KW - DEHYDRATION

KW - GLUCOSE

KW - BIOMASS

KW - ACID

KW - FRUCTOSE

KW - PLATFORM

U2 - 10.1002/cssc.201901115

DO - 10.1002/cssc.201901115

M3 - Article

VL - 12

SP - 4304

EP - 4312

JO - Chemsuschem

JF - Chemsuschem

SN - 1864-5631

IS - 18

ER -

ID: 118403681