High-Power Actuation from Molecular Photoswitches in Enantiomerically Paired Soft Springs

Asshoff, S. J., Lancia, F., Iamsaard, S., Matt, B., Kudernac, T., Fletcher, S. P. & Katsonis, N., 13-Mar-2017, In : Angewandte Chemie-International Edition. 56, 12, p. 3261-3265 5 p.

Research output: Contribution to journalArticleAcademicpeer-review

  • Sarah J. Asshoff
  • Federico Lancia
  • Supitchaya Iamsaard
  • Benjamin Matt
  • Tibor Kudernac
  • Stephen P. Fletcher
  • Nathalie Katsonis

Motion in plants often relies on dynamic helical systems as seen in coiling tendrils, spasmoneme springs, and the opening of chiral seedpods. Developing nanotechnology that would allow molecular-level phenomena to drive such movements in artificial systems remains a scientific challenge. Herein, we describe a soft device that uses nanoscale information to mimic seedpod opening. The system exploits a fundamental mechanism of stimuli-responsive deformation in plants, namely that inflexible elements with specific orientations are integrated into a stimuli-responsive matrix. The device is operated by isomerization of a light-responsive molecular switch that drives the twisting of strips of liquid-crystal elastomers. The strips twist in opposite directions and work against each other until the pod pops open from stress. This mechanism allows the photoisomerization of molecular switches to stimulate rapid shape changes at the macroscale and thus to maximize actuation power.

Original languageEnglish
Pages (from-to)3261-3265
Number of pages5
JournalAngewandte Chemie-International Edition
Issue number12
Publication statusPublished - 13-Mar-2017


  • helices, liquid-crystal elastomers, photochromic switches, smart materials, CRYSTAL POLYMER NETWORKS, SEED DISPERSAL, LIGHT, MECHANICS, GENERATION, COATINGS, MOTILITY, INSIGHTS, MOTORS, GLASSY

Download statistics

No data available

ID: 136166237