Publication

Hierarchical self-assembly of two-length-scale multiblock copolymers

ten Brinke, G., Loos, K., Vukovic, I. & du Sart, G. G., 20-Jul-2011, In : Journal of Physics-Condensed Matter. 23, 28, p. 284110-1-284110-6 6 p., 284110.

Research output: Contribution to journalArticleAcademicpeer-review

APA

ten Brinke, G., Loos, K., Vukovic, I., & du Sart, G. G. (2011). Hierarchical self-assembly of two-length-scale multiblock copolymers. Journal of Physics-Condensed Matter, 23(28), 284110-1-284110-6. [284110]. https://doi.org/10.1088/0953-8984/23/28/284110

Author

ten Brinke, Gerrit ; Loos, Katja ; Vukovic, Ivana ; du Sart, Gerrit Gobius. / Hierarchical self-assembly of two-length-scale multiblock copolymers. In: Journal of Physics-Condensed Matter. 2011 ; Vol. 23, No. 28. pp. 284110-1-284110-6.

Harvard

ten Brinke, G, Loos, K, Vukovic, I & du Sart, GG 2011, 'Hierarchical self-assembly of two-length-scale multiblock copolymers', Journal of Physics-Condensed Matter, vol. 23, no. 28, 284110, pp. 284110-1-284110-6. https://doi.org/10.1088/0953-8984/23/28/284110

Standard

Hierarchical self-assembly of two-length-scale multiblock copolymers. / ten Brinke, Gerrit; Loos, Katja; Vukovic, Ivana; du Sart, Gerrit Gobius.

In: Journal of Physics-Condensed Matter, Vol. 23, No. 28, 284110, 20.07.2011, p. 284110-1-284110-6.

Research output: Contribution to journalArticleAcademicpeer-review

Vancouver

ten Brinke G, Loos K, Vukovic I, du Sart GG. Hierarchical self-assembly of two-length-scale multiblock copolymers. Journal of Physics-Condensed Matter. 2011 Jul 20;23(28):284110-1-284110-6. 284110. https://doi.org/10.1088/0953-8984/23/28/284110


BibTeX

@article{3227f00f0ee54c0eb3d2535a99553e49,
title = "Hierarchical self-assembly of two-length-scale multiblock copolymers",
abstract = "The self-assembly in diblock copolymer-based supramolecules, obtained by hydrogen bonding short side chains to one of the blocks, as well as in two-length-scale linear terpolymers results in hierarchical structure formation. The orientation of the different domains, e. g. layers in the case of a lamellar-in-lamellar structure, is determined by the molecular architecture, graft-like versus linear, and the relative magnitude of the interactions involved. In both cases parallel and perpendicular arrangements have been observed. The comb-shaped supramolecules approach is ideally suited for the preparation of nanoporous structures. A bicontinuous morphology with the supramolecular comb block forming the channels was finally achieved by extending the original approach to suitable triblock copolymer-based supramolecules.",
keywords = "COMB-SHAPED SUPRAMOLECULES, POLYMER-SURFACTANT SYSTEMS, 2 LENGTH SCALES, BLOCK-COPOLYMERS, MICROPHASE SEPARATION, POLYSTYRENE, POLYANILINE, TRANSITIONS, MORPHOLOGY, PARALLEL",
author = "{ten Brinke}, Gerrit and Katja Loos and Ivana Vukovic and {du Sart}, {Gerrit Gobius}",
year = "2011",
month = "7",
day = "20",
doi = "10.1088/0953-8984/23/28/284110",
language = "English",
volume = "23",
pages = "284110--1--284110--6",
journal = "Journal of Physics-Condensed Matter",
issn = "0953-8984",
publisher = "IOP PUBLISHING LTD",
number = "28",

}

RIS

TY - JOUR

T1 - Hierarchical self-assembly of two-length-scale multiblock copolymers

AU - ten Brinke, Gerrit

AU - Loos, Katja

AU - Vukovic, Ivana

AU - du Sart, Gerrit Gobius

PY - 2011/7/20

Y1 - 2011/7/20

N2 - The self-assembly in diblock copolymer-based supramolecules, obtained by hydrogen bonding short side chains to one of the blocks, as well as in two-length-scale linear terpolymers results in hierarchical structure formation. The orientation of the different domains, e. g. layers in the case of a lamellar-in-lamellar structure, is determined by the molecular architecture, graft-like versus linear, and the relative magnitude of the interactions involved. In both cases parallel and perpendicular arrangements have been observed. The comb-shaped supramolecules approach is ideally suited for the preparation of nanoporous structures. A bicontinuous morphology with the supramolecular comb block forming the channels was finally achieved by extending the original approach to suitable triblock copolymer-based supramolecules.

AB - The self-assembly in diblock copolymer-based supramolecules, obtained by hydrogen bonding short side chains to one of the blocks, as well as in two-length-scale linear terpolymers results in hierarchical structure formation. The orientation of the different domains, e. g. layers in the case of a lamellar-in-lamellar structure, is determined by the molecular architecture, graft-like versus linear, and the relative magnitude of the interactions involved. In both cases parallel and perpendicular arrangements have been observed. The comb-shaped supramolecules approach is ideally suited for the preparation of nanoporous structures. A bicontinuous morphology with the supramolecular comb block forming the channels was finally achieved by extending the original approach to suitable triblock copolymer-based supramolecules.

KW - COMB-SHAPED SUPRAMOLECULES

KW - POLYMER-SURFACTANT SYSTEMS

KW - 2 LENGTH SCALES

KW - BLOCK-COPOLYMERS

KW - MICROPHASE SEPARATION

KW - POLYSTYRENE

KW - POLYANILINE

KW - TRANSITIONS

KW - MORPHOLOGY

KW - PARALLEL

U2 - 10.1088/0953-8984/23/28/284110

DO - 10.1088/0953-8984/23/28/284110

M3 - Article

VL - 23

SP - 284110-1-284110-6

JO - Journal of Physics-Condensed Matter

JF - Journal of Physics-Condensed Matter

SN - 0953-8984

IS - 28

M1 - 284110

ER -

ID: 5354133