Publication

Green Chemicals from d-glucose: Systematic Studies on Catalytic Effects of Inorganic Salts on the Chemo-Selectivity and Yield in Aqueous Solutions

Rasrendra, C. B., Makertihartha, I. G. B. N., Adisasmito, S. & Heeres, H. J., Sep-2010, In : Topics in Catalysis. 53, 15-18, p. 1241-1247 7 p.

Research output: Contribution to journalArticleAcademicpeer-review

APA

Rasrendra, C. B., Makertihartha, I. G. B. N., Adisasmito, S., & Heeres, H. J. (2010). Green Chemicals from d-glucose: Systematic Studies on Catalytic Effects of Inorganic Salts on the Chemo-Selectivity and Yield in Aqueous Solutions. Topics in Catalysis, 53(15-18), 1241-1247. https://doi.org/10.1007/s11244-010-9570-0

Author

Rasrendra, C. B. ; Makertihartha, I. G. B. N. ; Adisasmito, S. ; Heeres, H. J. / Green Chemicals from d-glucose : Systematic Studies on Catalytic Effects of Inorganic Salts on the Chemo-Selectivity and Yield in Aqueous Solutions. In: Topics in Catalysis. 2010 ; Vol. 53, No. 15-18. pp. 1241-1247.

Harvard

Rasrendra, CB, Makertihartha, IGBN, Adisasmito, S & Heeres, HJ 2010, 'Green Chemicals from d-glucose: Systematic Studies on Catalytic Effects of Inorganic Salts on the Chemo-Selectivity and Yield in Aqueous Solutions', Topics in Catalysis, vol. 53, no. 15-18, pp. 1241-1247. https://doi.org/10.1007/s11244-010-9570-0

Standard

Green Chemicals from d-glucose : Systematic Studies on Catalytic Effects of Inorganic Salts on the Chemo-Selectivity and Yield in Aqueous Solutions. / Rasrendra, C. B.; Makertihartha, I. G. B. N.; Adisasmito, S.; Heeres, H. J.

In: Topics in Catalysis, Vol. 53, No. 15-18, 09.2010, p. 1241-1247.

Research output: Contribution to journalArticleAcademicpeer-review

Vancouver

Rasrendra CB, Makertihartha IGBN, Adisasmito S, Heeres HJ. Green Chemicals from d-glucose: Systematic Studies on Catalytic Effects of Inorganic Salts on the Chemo-Selectivity and Yield in Aqueous Solutions. Topics in Catalysis. 2010 Sep;53(15-18):1241-1247. https://doi.org/10.1007/s11244-010-9570-0


BibTeX

@article{493e129b7db448459a373ac3a29ca740,
title = "Green Chemicals from d-glucose: Systematic Studies on Catalytic Effects of Inorganic Salts on the Chemo-Selectivity and Yield in Aqueous Solutions",
abstract = "The use of inorganic salts as catalysts for the reactions of d-glucose in aqueous solutions in a batch reactor is reported. The type of salt and effect of reaction time were examined in detail at a fixed salt (5 mM) and d-glucose concentration (0.1 M) and at a temperature of 140 A degrees C. Al(III) and Cr(II) salts gave the highest conversion of d-glucose. Typical reaction products were organic acids like lactic acid, levulinic acid, furanics like hydroxymethylfurfural and insoluble products (humins). The chemo-selectivity is a clear function of the type of inorganic salt. For Al(III), the major water soluble product was lactic acid, for Zn(II) HMF was formed in the highest yields. A reaction scheme is proposed to explain the observed product compositions.",
keywords = "Inorganic salts, Lewis acids, D-glucose, HMF, Levulinic acid, Lactic acid, Biobased chemicals, LACTIC-ACID PRODUCTION, LANTHANIDE(III) IONS, LEVULINIC ACID, CONVERSION, DEHYDRATION, BIOMASS, WATER, SOLVENTS, TRANSFORMATION, FRUCTOSE",
author = "Rasrendra, {C. B.} and Makertihartha, {I. G. B. N.} and S. Adisasmito and Heeres, {H. J.}",
year = "2010",
month = sep,
doi = "10.1007/s11244-010-9570-0",
language = "English",
volume = "53",
pages = "1241--1247",
journal = "Topics in Catalysis",
issn = "1022-5528",
publisher = "SPRINGER/PLENUM PUBLISHERS",
number = "15-18",

}

RIS

TY - JOUR

T1 - Green Chemicals from d-glucose

T2 - Systematic Studies on Catalytic Effects of Inorganic Salts on the Chemo-Selectivity and Yield in Aqueous Solutions

AU - Rasrendra, C. B.

AU - Makertihartha, I. G. B. N.

AU - Adisasmito, S.

AU - Heeres, H. J.

PY - 2010/9

Y1 - 2010/9

N2 - The use of inorganic salts as catalysts for the reactions of d-glucose in aqueous solutions in a batch reactor is reported. The type of salt and effect of reaction time were examined in detail at a fixed salt (5 mM) and d-glucose concentration (0.1 M) and at a temperature of 140 A degrees C. Al(III) and Cr(II) salts gave the highest conversion of d-glucose. Typical reaction products were organic acids like lactic acid, levulinic acid, furanics like hydroxymethylfurfural and insoluble products (humins). The chemo-selectivity is a clear function of the type of inorganic salt. For Al(III), the major water soluble product was lactic acid, for Zn(II) HMF was formed in the highest yields. A reaction scheme is proposed to explain the observed product compositions.

AB - The use of inorganic salts as catalysts for the reactions of d-glucose in aqueous solutions in a batch reactor is reported. The type of salt and effect of reaction time were examined in detail at a fixed salt (5 mM) and d-glucose concentration (0.1 M) and at a temperature of 140 A degrees C. Al(III) and Cr(II) salts gave the highest conversion of d-glucose. Typical reaction products were organic acids like lactic acid, levulinic acid, furanics like hydroxymethylfurfural and insoluble products (humins). The chemo-selectivity is a clear function of the type of inorganic salt. For Al(III), the major water soluble product was lactic acid, for Zn(II) HMF was formed in the highest yields. A reaction scheme is proposed to explain the observed product compositions.

KW - Inorganic salts

KW - Lewis acids

KW - D-glucose

KW - HMF

KW - Levulinic acid

KW - Lactic acid

KW - Biobased chemicals

KW - LACTIC-ACID PRODUCTION

KW - LANTHANIDE(III) IONS

KW - LEVULINIC ACID

KW - CONVERSION

KW - DEHYDRATION

KW - BIOMASS

KW - WATER

KW - SOLVENTS

KW - TRANSFORMATION

KW - FRUCTOSE

U2 - 10.1007/s11244-010-9570-0

DO - 10.1007/s11244-010-9570-0

M3 - Article

VL - 53

SP - 1241

EP - 1247

JO - Topics in Catalysis

JF - Topics in Catalysis

SN - 1022-5528

IS - 15-18

ER -

ID: 5128715