Publication

Gallium Oxide Nanorods: Novel, Template-Free Synthesis and High Catalytic Activity in Epoxidation Reactions

Lueangchaichaweng, W., Brooks, N. R., Fiorilli, S., Gobechiya, E., Lin, K., Li, L., Parres-Esclapez, S., Javon, E., Bals, S., Van Tendeloo, G., Martens, J. A., Kirschhock, C. E. A., Jacobs, P. A. & Pescarmona, P. P., 3-Feb-2014, In : Angewandte Chemie - International Edition. 53, 6, p. 1585-1589 5 p.

Research output: Contribution to journalArticleAcademicpeer-review

  • Warunee Lueangchaichaweng
  • Neil R. Brooks
  • Sonia Fiorilli
  • Elena Gobechiya
  • Kaifeng Lin
  • Li Li
  • Sonia Parres-Esclapez
  • Elsa Javon
  • Sara Bals
  • Gustaaf Van Tendeloo
  • Johan A. Martens
  • Christine E. A. Kirschhock
  • Pierre A. Jacobs
  • Paolo P. Pescarmona

Gallium oxide nanorods with unprecedented small dimensions (20-80nm length and 3-5nm width) were prepared using a novel, template-free synthesis method. This nanomaterial is an excellent heterogeneous catalyst for the sustainable epoxidation of alkenes with H2O2, rivaling the industrial benchmark microporous titanosilicate TS-1 with linear alkenes and being much superior with bulkier substrates. A thorough characterization study elucidated the correlation between the physicochemical properties of the gallium oxide nanorods and their catalytic performance, and underlined the importance of the nanorod morphology for generating a material with high specific surface area and a high number of accessible acid sites.

Original languageEnglish
Pages (from-to)1585-1589
Number of pages5
JournalAngewandte Chemie - International Edition
Volume53
Issue number6
Publication statusPublished - 3-Feb-2014
Externally publishedYes

    Keywords

  • epoxidation, gallium oxide, heterogeneous catalysis, hydrogen peroxide, nanorods, HYDROGEN-PEROXIDE, GAMMA-ALUMINA, OXIDATION, H2O2, BOEHMITE, ALKENES, GA2O3

ID: 13853211