Publication

An improved catalytic pyrolysis concept for renewable aromatics from biomass involving a recycling strategy for co-produced polycyclic aromatic hydrocarbons

Genuino, H. C., Muizebelt, I., Heeres, A., Schenk, N. J., Winkelman, J. G. M. & Heeres, H. J., 21-Jul-2019, In : Green Chemistry. 21, 14, p. 3802-3806 5 p.

Research output: Contribution to journalArticleAcademicpeer-review

APA

Genuino, H. C., Muizebelt, I., Heeres, A., Schenk, N. J., Winkelman, J. G. M., & Heeres, H. J. (2019). An improved catalytic pyrolysis concept for renewable aromatics from biomass involving a recycling strategy for co-produced polycyclic aromatic hydrocarbons. Green Chemistry, 21(14), 3802-3806. https://doi.org/10.1039/c9gc01485c

Author

Genuino, Homer C. ; Muizebelt, Inouk ; Heeres, Andre ; Schenk, Niels J. ; Winkelman, Jos G. M. ; Heeres, Hero J. / An improved catalytic pyrolysis concept for renewable aromatics from biomass involving a recycling strategy for co-produced polycyclic aromatic hydrocarbons. In: Green Chemistry. 2019 ; Vol. 21, No. 14. pp. 3802-3806.

Harvard

Genuino, HC, Muizebelt, I, Heeres, A, Schenk, NJ, Winkelman, JGM & Heeres, HJ 2019, 'An improved catalytic pyrolysis concept for renewable aromatics from biomass involving a recycling strategy for co-produced polycyclic aromatic hydrocarbons', Green Chemistry, vol. 21, no. 14, pp. 3802-3806. https://doi.org/10.1039/c9gc01485c

Standard

An improved catalytic pyrolysis concept for renewable aromatics from biomass involving a recycling strategy for co-produced polycyclic aromatic hydrocarbons. / Genuino, Homer C.; Muizebelt, Inouk; Heeres, Andre; Schenk, Niels J.; Winkelman, Jos G. M.; Heeres, Hero J.

In: Green Chemistry, Vol. 21, No. 14, 21.07.2019, p. 3802-3806.

Research output: Contribution to journalArticleAcademicpeer-review

Vancouver

Genuino HC, Muizebelt I, Heeres A, Schenk NJ, Winkelman JGM, Heeres HJ. An improved catalytic pyrolysis concept for renewable aromatics from biomass involving a recycling strategy for co-produced polycyclic aromatic hydrocarbons. Green Chemistry. 2019 Jul 21;21(14):3802-3806. https://doi.org/10.1039/c9gc01485c


BibTeX

@article{baf2df396cab45699cd923b0e625ef2a,
title = "An improved catalytic pyrolysis concept for renewable aromatics from biomass involving a recycling strategy for co-produced polycyclic aromatic hydrocarbons",
abstract = "Catalytic pyrolysis of crude glycerol over a shaped H-ZSM-5 zeolite catalyst with (partial) recycling of the product oil was studied with the incentive to improve benzene, toluene, and xylene (BTX) yields. Recycling of the polycyclic aromatic hydrocarbon (PAH) fraction, after separation from BTX by distillation and co-feeding with the crude glycerol feed, was shown to have a positive effect on the BTX yield. Further improvements were achieved by hydrogenation of the PAH fraction using a Ru/C catalyst and hydrogen gas prior to co-pyrolysis, and BTX yields up to 16 wt% on feed were obtained. The concept was also shown to be beneficial to other biomass feeds such as e.g., Kraft lignin, cellulose, and Jatropha oil.",
keywords = "P-XYLENE, BIO-OIL, CONVERSION, GLYCEROL, FURANICS, CRACKING, ZEOLITE, BTX",
author = "Genuino, {Homer C.} and Inouk Muizebelt and Andre Heeres and Schenk, {Niels J.} and Winkelman, {Jos G. M.} and Heeres, {Hero J.}",
year = "2019",
month = jul,
day = "21",
doi = "10.1039/c9gc01485c",
language = "English",
volume = "21",
pages = "3802--3806",
journal = "Green Chemistry",
issn = "1463-9262",
publisher = "ROYAL SOC CHEMISTRY",
number = "14",

}

RIS

TY - JOUR

T1 - An improved catalytic pyrolysis concept for renewable aromatics from biomass involving a recycling strategy for co-produced polycyclic aromatic hydrocarbons

AU - Genuino, Homer C.

AU - Muizebelt, Inouk

AU - Heeres, Andre

AU - Schenk, Niels J.

AU - Winkelman, Jos G. M.

AU - Heeres, Hero J.

PY - 2019/7/21

Y1 - 2019/7/21

N2 - Catalytic pyrolysis of crude glycerol over a shaped H-ZSM-5 zeolite catalyst with (partial) recycling of the product oil was studied with the incentive to improve benzene, toluene, and xylene (BTX) yields. Recycling of the polycyclic aromatic hydrocarbon (PAH) fraction, after separation from BTX by distillation and co-feeding with the crude glycerol feed, was shown to have a positive effect on the BTX yield. Further improvements were achieved by hydrogenation of the PAH fraction using a Ru/C catalyst and hydrogen gas prior to co-pyrolysis, and BTX yields up to 16 wt% on feed were obtained. The concept was also shown to be beneficial to other biomass feeds such as e.g., Kraft lignin, cellulose, and Jatropha oil.

AB - Catalytic pyrolysis of crude glycerol over a shaped H-ZSM-5 zeolite catalyst with (partial) recycling of the product oil was studied with the incentive to improve benzene, toluene, and xylene (BTX) yields. Recycling of the polycyclic aromatic hydrocarbon (PAH) fraction, after separation from BTX by distillation and co-feeding with the crude glycerol feed, was shown to have a positive effect on the BTX yield. Further improvements were achieved by hydrogenation of the PAH fraction using a Ru/C catalyst and hydrogen gas prior to co-pyrolysis, and BTX yields up to 16 wt% on feed were obtained. The concept was also shown to be beneficial to other biomass feeds such as e.g., Kraft lignin, cellulose, and Jatropha oil.

KW - P-XYLENE

KW - BIO-OIL

KW - CONVERSION

KW - GLYCEROL

KW - FURANICS

KW - CRACKING

KW - ZEOLITE

KW - BTX

U2 - 10.1039/c9gc01485c

DO - 10.1039/c9gc01485c

M3 - Article

VL - 21

SP - 3802

EP - 3806

JO - Green Chemistry

JF - Green Chemistry

SN - 1463-9262

IS - 14

ER -

ID: 118432557