Publication

Aluminum Complexes with Redox-Active Formazanate Ligand: Synthesis, Characterization, and Reduction Chemistry

Mondol, R. & Otten, E., 2019, In : Inorganic Chemistry. 58, 9, p. 6344-6355

Research output: Contribution to journalArticleAcademicpeer-review

APA

Mondol, R., & Otten, E. (2019). Aluminum Complexes with Redox-Active Formazanate Ligand: Synthesis, Characterization, and Reduction Chemistry. Inorganic Chemistry, 58(9), 6344-6355. https://doi.org/10.1021/acs.inorgchem.9b00553

Author

Mondol, Ranajit ; Otten, Edwin. / Aluminum Complexes with Redox-Active Formazanate Ligand : Synthesis, Characterization, and Reduction Chemistry. In: Inorganic Chemistry. 2019 ; Vol. 58, No. 9. pp. 6344-6355.

Harvard

Mondol, R & Otten, E 2019, 'Aluminum Complexes with Redox-Active Formazanate Ligand: Synthesis, Characterization, and Reduction Chemistry', Inorganic Chemistry, vol. 58, no. 9, pp. 6344-6355. https://doi.org/10.1021/acs.inorgchem.9b00553

Standard

Aluminum Complexes with Redox-Active Formazanate Ligand : Synthesis, Characterization, and Reduction Chemistry. / Mondol, Ranajit; Otten, Edwin.

In: Inorganic Chemistry, Vol. 58, No. 9, 2019, p. 6344-6355.

Research output: Contribution to journalArticleAcademicpeer-review

Vancouver

Mondol R, Otten E. Aluminum Complexes with Redox-Active Formazanate Ligand: Synthesis, Characterization, and Reduction Chemistry. Inorganic Chemistry. 2019;58(9):6344-6355. https://doi.org/10.1021/acs.inorgchem.9b00553


BibTeX

@article{f0bad73bab5448d7a1caa60e4a4c173a,
title = "Aluminum Complexes with Redox-Active Formazanate Ligand: Synthesis, Characterization, and Reduction Chemistry",
abstract = "The synthesis of aluminum complexes with redox-active formazanate ligands is described. Salt metathesis using AlCl3 was shown to form a five-coordinate complex with two formazanate ligands, whereas organometallic aluminum starting materials yield tetrahedral mono(formazanate) aluminum compounds. The aluminum diphenyl derivative was successfully converted to the iodide complex (formazanate)AlI2, and a comparison of spectroscopic/structural data for these new complexes is provided. Characterization by cyclic voltammetry is supplemented by chemical reduction to demonstrate that ligand-based redox reactions are accessible in these compounds. The possibility to obtain a formazanate aluminum(I) carbenoid species by two-electron reduction was examined by experimental and computational studies, which highlight the potential impact of the nitrogen-rich formazanate ligand on the electronic structure of compounds with this ligand.",
author = "Ranajit Mondol and Edwin Otten",
year = "2019",
doi = "10.1021/acs.inorgchem.9b00553",
language = "English",
volume = "58",
pages = "6344--6355",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "AMER CHEMICAL SOC",
number = "9",

}

RIS

TY - JOUR

T1 - Aluminum Complexes with Redox-Active Formazanate Ligand

T2 - Synthesis, Characterization, and Reduction Chemistry

AU - Mondol, Ranajit

AU - Otten, Edwin

PY - 2019

Y1 - 2019

N2 - The synthesis of aluminum complexes with redox-active formazanate ligands is described. Salt metathesis using AlCl3 was shown to form a five-coordinate complex with two formazanate ligands, whereas organometallic aluminum starting materials yield tetrahedral mono(formazanate) aluminum compounds. The aluminum diphenyl derivative was successfully converted to the iodide complex (formazanate)AlI2, and a comparison of spectroscopic/structural data for these new complexes is provided. Characterization by cyclic voltammetry is supplemented by chemical reduction to demonstrate that ligand-based redox reactions are accessible in these compounds. The possibility to obtain a formazanate aluminum(I) carbenoid species by two-electron reduction was examined by experimental and computational studies, which highlight the potential impact of the nitrogen-rich formazanate ligand on the electronic structure of compounds with this ligand.

AB - The synthesis of aluminum complexes with redox-active formazanate ligands is described. Salt metathesis using AlCl3 was shown to form a five-coordinate complex with two formazanate ligands, whereas organometallic aluminum starting materials yield tetrahedral mono(formazanate) aluminum compounds. The aluminum diphenyl derivative was successfully converted to the iodide complex (formazanate)AlI2, and a comparison of spectroscopic/structural data for these new complexes is provided. Characterization by cyclic voltammetry is supplemented by chemical reduction to demonstrate that ligand-based redox reactions are accessible in these compounds. The possibility to obtain a formazanate aluminum(I) carbenoid species by two-electron reduction was examined by experimental and computational studies, which highlight the potential impact of the nitrogen-rich formazanate ligand on the electronic structure of compounds with this ligand.

U2 - 10.1021/acs.inorgchem.9b00553

DO - 10.1021/acs.inorgchem.9b00553

M3 - Article

VL - 58

SP - 6344

EP - 6355

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 9

ER -

ID: 79891690