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Publications
Journal Articles201175. Kwiat M, Elnathan R, Kwak M, de Vries JW, Pevzner A, Engel Y, Burstein L, Khatchtourints A, Lichtenstein A, Flaxer E, Herrmann A, Patolsky F: Non-covalent Monolayer-Piercing Anchoring of Lipophilic Nucleic Acids: Preparation, Characterization, and Sensing Applications : J. Am. Chem. Soc. 2011, online. 74. Kwak M, Herrmann A: Nucleic acid amphiphiles: synthesis and self-assembled nanostructures : Chem. Soc. Rev. 2011, 40: 5745-5755. 73. Kwak M, Gao J, Prusty DK, Musser AJ, Markov VA, Tombros N, Stuart MCA, Browne WR, Boekema EJ, ten Brinke G, Jonkman HT, van Wees BJ, Loi MA, Herrmann A: DNA Block Copolymer Doing It All: From Selection to Self-Assembly of Semiconducting Carbon Nanotubes : Angew. Chem. Int. Ed. 2011, 50: 3206-3210. 72. Ayaz MS†, Kwak M†, Alemdaroglu FE, Wang J, Berger R, Herrmann A: Synthesis of DNA Block Copolymers with Extended Nucleic Acid Segments by Enzymatic Ligation: Cut and Paste Large Hybrid Architectures : Chem. Commun. 2010, 47: 2243-2245 († equal contribution, featured on a front cover). 71. Gao J, Kwak M, Wildeman J, Herrmann A, Loi MA: Effectiveness of Sorting Single-Walled Carbon Nanotubes by Diameter Using Polyfluorene Derivatives : Carbon 2011, 49: 333-338. 70. Kolbe A, del Mercato LL, Abbasi AZ, Rivera Gil P, Gorzini SJ, Huibers WHC, Poolman A, Parak WJ, Herrmann A: De Novo Design of Supercharged, Unfolded Protein Polymers, and Their Assembly into Supramolecular Aggregates : Macromol. Rapid. Commun. 2011, 32: 186-190. (featured in Materials Views 2011).
201069. Anaya M, Kwak M, Musser AJ, Müllen K, Herrmann A: Tunable Hydrophobicity in DNA micelles: design, synthesis, and characterization of a new family of DNA amphiphiles : Chem. Eur. J. 2010, 16: 12852-12859. 68. Prusty DK, Herrmann A: A Fluorogenic reaction based on heavy-atom removal for ultrasensitive DNA detection : J. Am. Chem. Soc. 2010, 132: 12197-12199. 67. Kwak M, Musser AJ, Lee J, Herrmann A: DNA-functionalised blend micelles: mix and fix polymeric hybrid nanostructures : Chem. Commun. 2010, 46: 4935-4937. 66. Kwak M, Minten IJ, Anaya D-M, Musser A J, Brasch M, Nolte RJM, Müllen K, Cornelissen JJLM, Herrmann A: Virus-like Particles Templated by DNA Micelles: A General Method for Loading Virus Nanocarriers : J. Am. Chem. Soc. 2010, 132 : 7834-7835 (highlighted in Angew. Chem. 2010). 65. Kwak M, Herrmann A: Nucleic Acid/Organic Polymer Hybrid Materials: Synthesis, Superstructures and Applications : Angew. Chem. Int. Ed. 2010, 46: 8574-8587 (invited review). 64. Sowwan M, Faroun M, Mentovich E, Ibrahim I, Haboush S, Alemdaroglu FE, Kwak M, Richter S, Herrmann A: Polarizability of DNA block copolymer nanoparticles observed by electrostatic force microscopy : Macromol. Rapid Comm. 2010, 31: 1242-1246. 63. Peneva K, Gundlach K, Herrmann A, Paulsen H, Müllen K: Site-specific incorporation of perylene into an N-terminally modified light-harvesting complex II: Org. Biomol. Chem. 2010, 8: 4823 - 4826. 62. Cordes T, Vogelsang J, Anaya M, Spagnuolo C, Gietl A, Summerer W, Herrmann A, Müllen K, Tinnefeld P: Single-Molecule Redox Blinking of Perylene Diimide Derivatives in Water: J. Am. Chem. Soc. 2010, 132: 2404-2409.
200961. Yasukuni R, Sliwa M, Hofkens J, De Schryver FC, Herrmann A, Müllen K, Asahi : Size-Dependent Optical Properties of Dendronized Perylenediimide Nanoparticle Prepared by Laser Ablation in Water: Japanese Journal of Applied Physics 2009, 48: 065002.60. Li C, Schneboom J, Liu ZH, Pschirer NG, Erk P,Herrmann A,Müllen: Rainbow Perylene Monoimids: Easy Control of Optical Properties: Chem. Eur. J. 2009, 15: 878-884. 59. Alemdaroglu FE, Alexander SC, Ji D, Prusty, DK, Boersch M, HerrmannA: Poly(BODIPY)s: A New Class of Tunable Polymeric Dyes: Macromolecules 2009, 42: 6529-6536. 58.Wei Z, Zphel L, Wang J, Berger R, Rabe JP, Herrmann A: Generation of Multiblock Copolymers by PCR: Synthesis, Visualization and Nanomechanical Properties: Nano Lett. 2009, 9: 36583662. 57. Li C, Liu Z, Schneboom J, Eickemyer F. Pschirer NG, Erk P, Herrmann A, Müllen K: Perylenes as sensitizers in hybrid solar cells: how molecular size influences performance: J. Mat. Chem. 2009, 19: 5405-5415. 56. Modesti G, Zimmermann B, Brsch M, Herrmann A, Saalwchter K: Diffusion in Model Networks as Studied by NMR and FCS: Macromolecules 2009, 42: 4681-4689. 55. Rocha S, Hutchison JA, Peneva K, Herrmann A, Müllen K, Skjot M, Jorgensen CI, Svendsen A, DeSchryver FC, Hofkens J, Uji-I H: Linking Phospholipase Mobility to Activity by Single-Molecule Wide-Field Microscopy: ChemPhysChem 2009, 10: 151-161.
200854. Yasukuni R, Asahi T, Sugiyama T, Masuhara H, Sliwa M, Hofkens J, De Schryver FC, Van der Auweraer M, Herrmann A, Müllen K: Fabrication of fluorescent nanoparticles of dendronized perylenediimide by laser ablation in water: Applied Physics A: Materials Science & Processing 2008, 93: 5-9. 53. Li C, Yum J-H, Moon SJ, Herrmann A, Eickemeyer F, Pschirer NG, Erk P, Schneboom J, Grtzel M, Nazeeruddin MK: An improved perylene sensitizer for solar cell applications: ChemSusChem 2008, 1: 615-618. 52. Fron E, Pilot R, Schweitzer G, Qu JQ, Herrmann A, Müllen K, Hofkens J, van der Auweraer M, De Schryver FC: Photoinduced electron-transfer in perylenediimide triphenylamine-based dendrimers: single photon timing and femtosecond transient absorption spectroscopy: Photochemical & Photobiological Sciences 2008, 7:597-604. 51. Liu Z, Li C, Wagner M, Avlasevich Y, Herrmann A, Müllen K: Amino-substituted rylene dicarboximides and their quinoidal charge delocalization after deprotonation: Chem. Commun. 2008, 5028-5030. 50. Jaiser F, Neher D, Meisel A, Nothofer H-G, Miteva T, Herrmann A, Müllen K, Scherf U: Energy and charge transfer in blends of dendronized perylenes with polyfluorene: J. Chem. Phys. 2008, 129: 114901. 49.PenevaK, Mihov G, Nolde F, Rocha S, Hotta J, Braeckmans K, Hofkens J, Uji-I H Herrmann A, Müllen K: Water-soluble monofunctional perylene and terrylene dyes: powerful labels for single enzyme tracking: Angew. Chem. Int. Ed. 2008, 47: 3372-3375. 2008, : 3372-3375. 48. Wang J., Alemdaroglu FE, Prusty DK, HerrmannA, Berger R: In-situ visualization of the enzymatic growth of surface immobilized DNA block copolymer micelles by scanning force microscopy: Macromolecules 2008, 41: 2914-2919. 47. PenevaK, Mihov G, Herrmann A, Zarrabi N, Brsch M, Thomas Duncan T, Müllen K: Exploiting the nitrilotriacetic acid moiety for biolabelling with ultrastable perylene dyes: J. Am. Chem. Soc. 2008, 130: 5398-5399. 46. Wll D., Uji-I H., Schnitzler T, Hotta J, DedeckerP, Herrmann A, DeSchryver FC, Müllen K, Hofkens J: Radical Polymerization Tracked by Single Molecule Spectroscopy: Angew. Chem. Int. Ed. 2008, 47: 783-787. 45. Alemdaroglu FE, Alemdaroglu CN, Langguth P, HerrmannA: DNA Block Copolymer Micelles A Combinatorial Tool for Cancer Nanotechnology: : Adv. Mat. 2008, 20: 899-902. 44. Alemdaroglu FE, Alemdaroglu CN, Langguth P, HerrmannA: Shape Dependent Cellular Uptake of DNA Nanoparticles: Macromol. Rapid Commun. 2008, 29: 326-329. 43. Alemdaroglu FE, Wang J. Brsch M, Berger R, HerrmannA: Enzymatic Control of the Size of DNA Block Copolymer Nanoparticles: Angew. Chem. Int. Ed. 2008, 47: 974-976.
2007 - Groningen42. Edvinsson T, Li C, Pschirer N, Schoneboom J, Eickemeyer F, Sens R, Boschloo G, Herrmann A, Müllen K, Hagfeldt A: Intramolecular charge-transfer tuning of perylenes: Spectroscopic features and performance in Dye-sensitized solar cells: J. Phys.Chem. C 2007, 111: 15137-15140. 41. Ding K, Alemdaroglu FE, Brsch M, Berger R, HerrmannA: Engineering the Structural Properties of DNA Block Copolymer Micelles by Molecular Recognition: Angew. Chem. Int. Ed. 2007, 46: 1172-1175. 40. Alemdaroglu FE, Safak M, Berger R, HerrmannA: DNA Block Copolymers: Chem. Commun. 2007, 1358-1359. 39. Safak M, Alemdaroglu FE, Li Y, Ergen E, HerrmannA: Polymerase Chain Reaction as a Novel Tool for the Preparation of Block Copolymers: Adv. Mat. 2007, 19: 1499-1505. 38. Alemdaroglu FE, HerrmannA: DNA Meets Synthetic Polymers Highly Versatile Hybrid Materials: Org. Biomol. Chem. 2007, 5: 1311 - 1320. (Invited Review) 37. Flors C, Oesterling I, Schnitzler T, Fron E, Schweitzer G, Sliwa M, Herrmann A, van der Auweraer M, de Schryver FC, Müllen K, Hofkens J: Energy and electron transfer in ethynylene bridged perylene diimide multichromophores: J. Phys. Chem. C 2007, 111: 4861-4870. 36. Tang TJ, Herrmann A, Peneva K, Müllen K, Webber S: Energy transfer in molecular layer-by-layer films of water-soluble perylene diimides: Langmuir 2007, 23: 4623-4628. 35. Margineanu A., Hotta J., Van der Auweraer M., Ameloot M., Stefan A., Beljonne D., Engelborghs Y., Herrmann A., Müllen K., De Schryver F. C., Hofkens J.: Visualization of Membrane Rafts Using a Perylene Monoimide Derivative and Fluorescence Lifetime Imaging: Biophys. J. 2007, 93: 2877-2891. 34. Alemdaroglu FE, Ding K, Berger R, HerrmannA: DNA-Templated Synthesis in Three Dimensions: Introducing a Micellar Scaffold for Organic Reactions: Angew. Chem. Int. Ed. 2007, 46: 1172-1175.
2006 to 199933. Ergen E, Weber M, Jacob J, Herrmann A, Müllen K: Twin probes as a novel tool for the detection of single-nucleotide polymorphisms: Chem. Eur. J. 2006, 12: 3707-3713. (Rated as very important paper) 32. Palermo V, Morelli S, Palma M, Simpson C, Nolde F, Herrmann A, Müllen K, Samori P: Nanoscale structural and electronic properties of ultrathin blends of two polyaromatic molecules: A Kelvin Probe Force Microscopy investigation: ChemPhysChem 2006, 7: 847-853. 31. Uji-I H, Melnikov SM, Deres A, Bergamini G, De Schryver F, Herrmann A, Müllen K, Enderlein J, Hofkens J: Visualizing spatial and temporal heterogeneity of single molecule rotational diffusion in a glassy polymer by defocused wide-field imaging: Polymer 2006, 47: 2511-2518. 30. Herrmann A, Müllen K: From Industrial Colorants to Single Photon Sources and Biolabels: The Fascination and Function of Rylene Dyes: Chem. Lett. 2006, 35: 978-986. 29. Mihov G, Grebel-Koehler D, Lbbert A, Vandermeulen GWM, Herrmann A, Klok HA, Müllen K: Polyphenylene dendrimers as scaffolds for shape-persistent multiple peptide conjugates. Bioconjugate Chem. 2005, 16: 283-293. 28. Chaltin P, Margineanu A, Marchand D, Van Aerschot A, Rozenski J, De Schryver F, Herrmann A, Müllen K, Juliano R, Fisher MH, Kang HM, De Feyter S, Herdewijn P: Delivery of antisense oligonucleotides using cholesterol-modified sense dendrimers and cationic lipids. Bioconjugate Chem. 2005, 16: 827-836. 2005, : 827-836. 27. Haase M, Hbner CG, Reuther E, Herrmann A, Müllen K, Basche T: Exponential and power-law kinetics in single-molecule fluorescence intermittency. J. Phys. Chem. B 2004, 108: 10445-10450. 26. Lippitz M, Hbner CG, Christ T, Eichner H, Bordat P, Herrmann A, Müllen K, Basche T: Coherent electronic coupling versus localization in individual molecular dimmers. Phys. Rev. Lett. 2004, 92: 103001. 25. Herrmann A, Mihov G, Vandermeulen GWM, Klok HA, Müllen K: Peptide-functionalized polyphenylene dendrimers. Tetrahedron 2003, 59:3925-3935. 23. Hubner CG, Zumofen G, Renn A, Herrmann A, Mullen K, Basche T: Photon antibunching and collective effects in the fluorescence of single bichromophoric molecules. Phys. Rev. Lett. 2003, 91:Art. No. 093903. 22. Liu DJ, De Feyter S, Cotlet M, Wiesler UM, Weil T, Herrmann A, Müllen K, De Schryver FC: Fluorescent self-assembled polyphenylene dendrimer nanofibers. Macromolecules 2003, 36:8489-8498. 21. Jordens S, De Belder G, Lor M, Schweitzer G, Van der Auweraer M, Weil T, Herrmann A, Wiesler UM, Müllen K, De Schryver FC: Generation dependent singlet-singlet annihilation within multichromophoric dendrimers studied by polychromatic transient absorption. Photochemical & Photobiological Sciences 2003, 2:1118-1124. 20. Christ T, Petzke F, Bordat P, Herrmann A, Reuther E, Müllen K, Basche T: Investigation of molecular dimers by ensemble and single molecule spectroscopy. J. Luminescence 2002, 98:23-33. 19. Lor M, De R, Jordens S, De Belder G, Schweitzer G, Cotlet M, Hofkens J, Weil T, Herrmann A, Müllen K, De Schryver FC: Generation-dependent energy dissipation in rigid dendrimers studied by femtosecond to nanosecond time-resolved fluorescence spectroscopy. J. Phys. Chem. A 2002, 106:2083-2090. 18. De Belder G, Jordens S, Lor M, Schweitzer G, De R, Weil T, Herrmann A, Wiesler UK, Müllen K, De Schryver FC: Femtosecond fluorescence upconversion study of rigid dendrimers containing peryleneimide chromophores at the rim. Journal of Photochem. Photobiology A-Chemistry 2001, 145:61-70. 17. De Belder G, Schweitzer G, Jordens S, Lor M, Mitra S, Hofkens J, De Feyter S, Van der Auweraer M, Herrmann A, Weil T, et al.: Singlet-singlet annihilation in multichromophoric peryleneimide dendrimers, determined by fluorescence upconversion. Chemphyschem 2001, 2:49-55. 16. Gensch T, Hofkens J, Kohn J, Vosch T, Herrmann A, Müllen K, De Schryver FC: Polarisation sensitive single molecule fluorescence detection with linear polarised excitation light and modulated polarisation direction applied to multichromophoric entities. Single Molecules 2001, 2:35-44. 15. Herrmann A, Weil T, Sinigersky V, Wiesler UM, Vosch T, Hofkens J, De Schryver FC, Müllen K: Polyphenylene dendrimers with perylene diimide as a luminescent core. Chem. Eur. J. 2001, 7:4844-4853. 14. Hofkens J, Schroeyers W, Loos D, Cotlet M, Kohn F, Vosch T, Maus M, Herrmann A, Müllen K, Gensch T, De Schryver FC: Triplet states as non-radiative traps in multichromophoric entities: single molecule spectroscopy of an artificial and natural antenna system. Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy 2001, 57:2093-2107. 13. Hofkens J, Vosch T, Maus M, Kohn F, Cotlet M, Weil T, Herrmann A, Müllen K, De Schryver FC: Conformational rearrangements in and twisting of a single molecule. Chem. Phys. Lett. 2001, 333:255-263. 12. Maus M, De R, Lor M, Weil T, Mitra S, Wiesler UM, Herrmann A, Hofkens J, Vosch T, Müllen K, De Schryver FC: Intramolecular energy hopping and energy trapping in polyphenylene dendrimers with multiple peryleneimide donor chromophores and a terryleneimide acceptor trap chromophore. J. Am. Chem. Soc. 2001, 123:7668-7676. 11. Maus M, Mitra S, Lor M, Hofkens J, Weil T, Herrmann A, Müllen K, De Schryver FC: Intramolecular energy hopping in polyphenylene dendrimers with an increasing number of peryleneimide chromophores. J. Phys. Chem. A 2001, 105:3961-3966. 10. Schmelz O, Mews A, Basche T, Herrmann A, Müllen K: Supramolecular complexes from CdSe nanocrystals and organic fluorophors. Langmuir 2001, 17:2861-2865. 9. Vosch T, Hofkens J, Cotlet M, Kohn F, Fujiwara H, Gronheid R, Van Der Biest K, Weil T, Herrmann A, Müllen K, De Schryver FC: Influence of structural and rotational isomerism on the triplet blinking of individual dendrimer molecules. Angew. Chem. Int. Ed. 2001, 40:4643. 8. Weil T, Wiesler UM, Herrmann A, Bauer R, Hofkens J, De Schryver FC, Müllen K: Polyphenylene dendrimers with different fluorescent chromophores asymmetrically distributed at the periphery. J. Am. Chem. Soc. 2001, 123:8101-8108. 7. Hofkens J, Maus M, Gensch T, Vosch T, Cotlet M, Kohn F, Herrmann A, Müllen K, De Schryver F: Probing photophysical processes in individual multichromophoric dendrimers by single-molecule spectroscopy. J. Am. Chem. Soc.2000, 122:9278-9288. 6. Stork M, Herrmann A, Nemnich T, Klapper M, Müllen K: Combinatorial testing of supported catalysts for the heterogeneous polymerization of olefins. Angew. Chem. Int. Ed. 2000, 39:4367. 5. Gensch T, Hofkens J, Herrmann A, Tsuda K, Verheijen W, Vosch T, Christ T, Basche T, Müllen K, De Schryver FC: Fluorescence detection from single dendrimers with multiple chromophores. Angew. Chem. Int. Ed. 1999, 38:3752-3756. 4. Karni Y, Jordens S, De Belder G, Hofkens J, Schweitzer G, De Schryver FC, Herrmann A, Müllen K: Correlation between ground state conformation and excited state dynamics in a multichromophoric dendrimer studied by excitation wavelength dependent fluorescence upconversion. J. Phys. Chem. B 1999, 103:9378-9381. 3. Karni Y, Jordens S, De Belder G, Schweitzer G, Hofkens J, Gensch T, Maus M, De Schryver FC, Herrmann A, Müllen K: Intramolecular evolution from a locally excited state to an excimer-like state in a multichromophoric dendrimer evidenced by a femotosecond fluorescence upconversion study. Chem. Phys. Lett. 1999, 310:73-78. 2. Lee SK, Zu YB, Herrmann A, Geerts Y, Müllen K, Bard AJ: Electrochemistry, spectroscopy and electrogenerated chemiluminescence of perylene, terrylene, and quaterrylene diimides in aprotic solution. J. Am. Chem. Soc.1999, 121:3513-3520. 1. Gohde W, Fischer UC, Fuchs H, Tittel J, Basche T, Bruchle C, Herrmann A, Müllen K: Fluorescence blinking and photobleaching of single terrylenediimide molecules studied with a confocal microscope. J. Phys. Chem. A 1998, 102:9109-9116. Book chapter1. G. Schweitzer, G. De Belder, S. Jordens, M. Lor, K. Mllen, A. Herrmann, F. C. De Schryver: Femtosecond Time-Resolved Fluorescence and Anisotropy Decay Spectroscopy of a Dendrimer with Eight Chromophores at the Rim, Femtochemistry 2001, VCH-Wiley, Chapter 17, 295-306. 2. Zimmermann J, Kwak M, Musser AJ, Herrmann A: Amphiphilic DNA Block Copolymers: Nucleic Acid-Polymer Hybrid Materials for Diagnostics and Biomedicine: in Methods in Molecular Biology: Bioconjugation Protocols, 2011, Springer, Heidelberg, Chapter 15, 239-266. Patents1. Herrmann A, Stork M, Klapper M, Müllen K: Deutsche Patentanmeldung Nr. 199 27 482.7 (1999)Verfahren zur Herstellung von gefrbten Polymeren 2. Stork M, Herrmann A, Klapper M, Müllen K: Deutsche Patentanmeldung Nr. 199 27 483.5 (1999) Polymerisationsverfahren unter Verwendung unterschiedlich markierter Katalysatoren 3. Ergen E, Herrmann A, Müllen K: Deutsche Patentanmeldung submitted 21st December 2004, File number: 04 03 0341.4,Verfahren zur sequenzspezifischen Detektion von DNA 4. Herrmann A, Alemdaroglu FE, Müllen K, Alemdaroglu NC, Langguth P: European Patent Application 2008, File number: 070159009-1216, Targeted block copolymer micelles
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